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[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate

Abdel-Magied, Ahmed; Singh, Amrendra LU ; Haukka, Matti and Nordlander, Ebbe LU (2011) In Acta Crystallographica Section E: Structure Reports Online 67(12). p.1601-1816
Abstract
In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
67
issue
12
pages
1601 - 1816
publisher
Wiley-Blackwell
external identifiers
  • wos:000298795300129
  • scopus:83155184854
ISSN
1600-5368
DOI
10.1107/S1600536811049312
language
English
LU publication?
yes
id
4025bb82-aca3-4a7c-b9ed-ab7d558ea290 (old id 2345073)
date added to LUP
2012-02-24 13:13:17
date last changed
2017-01-01 06:16:24
@article{4025bb82-aca3-4a7c-b9ed-ab7d558ea290,
  abstract     = {In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.},
  author       = {Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Nordlander, Ebbe},
  issn         = {1600-5368},
  language     = {eng},
  number       = {12},
  pages        = {1601--1816},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate},
  url          = {http://dx.doi.org/10.1107/S1600536811049312},
  volume       = {67},
  year         = {2011},
}