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[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate

Abdel-Magied, Ahmed ; Singh, Amrendra LU ; Haukka, Matti and Nordlander, Ebbe LU (2011) In Acta Crystallographica Section E: Structure Reports Online 67(12). p.1601-1816
Abstract
In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
67
issue
12
pages
1601 - 1816
publisher
International Union of Crystallography
external identifiers
  • wos:000298795300129
  • scopus:83155184854
ISSN
1600-5368
DOI
10.1107/S1600536811049312
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
4025bb82-aca3-4a7c-b9ed-ab7d558ea290 (old id 2345073)
date added to LUP
2016-04-01 14:29:41
date last changed
2021-02-17 06:49:36
@article{4025bb82-aca3-4a7c-b9ed-ab7d558ea290,
  abstract     = {In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.},
  author       = {Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Nordlander, Ebbe},
  issn         = {1600-5368},
  language     = {eng},
  number       = {12},
  pages        = {1601--1816},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate},
  url          = {http://dx.doi.org/10.1107/S1600536811049312},
  doi          = {10.1107/S1600536811049312},
  volume       = {67},
  year         = {2011},
}