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From localised to delocalised electronic states in free Ar, Kr and Xe clusters

Feifel, R; Tchaplyguine, Maxim LU ; Ohrwall, G; Salonen, M; Lundwall, M; Marinho, RRT; Gisselbrecht, Mathieu LU ; Ristinmaa Sörensen, Stacey LU ; de Brito, AN and Karlsson, L, et al. (2004) In European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics1998-01-01+01:00 30(3). p.343-351
Abstract
We present new results for the inner valence levels of clusters of the three inert gases Ar, Kr and Xe based on photoelectron spectroscopy studies. The inner valence levels are compared to the localised core levels and to the delocalised outer valence levels. This comparison shows a gradual change from a relatively localised behaviour for Ar inner valence 3s, over the intermediate case of Kr inner valence 4s, to a more delocalised behaviour for Xe inner valence 5s. This change correlates well with the ratio between the orbital sizes and the interatomic distances. The Kr4s intermediate case is found to exhibit characteristics of both localised and delocalised behaviour.
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Contribution to journal
publication status
published
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in
European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics1998-01-01+01:00
volume
30
issue
3
pages
343 - 351
publisher
EDP Sciences
external identifiers
  • wos:000224301400006
  • scopus:4944219653
ISSN
1434-6060
DOI
10.1140/epjd/e2004-00103-6
language
English
LU publication?
yes
id
c4249210-dd1c-48c0-8c9f-bcc7a7774094 (old id 266510)
date added to LUP
2007-10-22 18:10:13
date last changed
2017-09-24 04:29:50
@article{c4249210-dd1c-48c0-8c9f-bcc7a7774094,
  abstract     = {We present new results for the inner valence levels of clusters of the three inert gases Ar, Kr and Xe based on photoelectron spectroscopy studies. The inner valence levels are compared to the localised core levels and to the delocalised outer valence levels. This comparison shows a gradual change from a relatively localised behaviour for Ar inner valence 3s, over the intermediate case of Kr inner valence 4s, to a more delocalised behaviour for Xe inner valence 5s. This change correlates well with the ratio between the orbital sizes and the interatomic distances. The Kr4s intermediate case is found to exhibit characteristics of both localised and delocalised behaviour.},
  author       = {Feifel, R and Tchaplyguine, Maxim and Ohrwall, G and Salonen, M and Lundwall, M and Marinho, RRT and Gisselbrecht, Mathieu and Ristinmaa Sörensen, Stacey and de Brito, AN and Karlsson, L and Martensson, N and Svensson, S and Bjorneholm, O},
  issn         = {1434-6060},
  language     = {eng},
  number       = {3},
  pages        = {343--351},
  publisher    = {EDP Sciences},
  series       = {European Physical Journal D. Atomic, Molecular, Optical and Plasma Physics1998-01-01+01:00},
  title        = {From localised to delocalised electronic states in free Ar, Kr and Xe clusters},
  url          = {http://dx.doi.org/10.1140/epjd/e2004-00103-6},
  volume       = {30},
  year         = {2004},
}