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Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light

Xia, Lixin; Hu, Xinhu; Sun, Mengtao; Li, Jushi; Yang, Donghui; Wang, Xiaofang and Xu, Hongxing LU (2012) In Journal of Raman Spectroscopy 43(8). p.1024-1028
Abstract
For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
2, 4-dinitrobenzenethiol, 4-chloro-2-nitrobenzenethiol, silver colloids, surface-enhanced Raman scattering spectroscopy, selective photoreduction
in
Journal of Raman Spectroscopy
volume
43
issue
8
pages
1024 - 1028
publisher
John Wiley & Sons
external identifiers
  • wos:000307550100010
  • scopus:84865172776
ISSN
1097-4555
DOI
10.1002/jrs.3143
language
English
LU publication?
yes
id
a6733874-1624-48c1-87db-95112e5f4b0f (old id 3059769)
date added to LUP
2012-09-26 09:55:38
date last changed
2017-01-01 06:21:48
@article{a6733874-1624-48c1-87db-95112e5f4b0f,
  abstract     = {For the first time, we report experimentally and theoretically that nitroaromatic compounds, 2,4-dinitrobenzenethiol and 4-chloro-2-nitrobenzenethiol, on silver sols can be selectively reduced to 2-amino-4-nitrobenzenethiol and 2-amino-4-chlorobenzenethiol simply by irradiating with a visible light in ambient conditions, and the selective photoreduction is a very facile process. The results of quantum chemical calculations are in good agreement with our experimental data. Copyright (c) 2012 John Wiley & Sons, Ltd.},
  author       = {Xia, Lixin and Hu, Xinhu and Sun, Mengtao and Li, Jushi and Yang, Donghui and Wang, Xiaofang and Xu, Hongxing},
  issn         = {1097-4555},
  keyword      = {2,4-dinitrobenzenethiol,4-chloro-2-nitrobenzenethiol,silver colloids,surface-enhanced Raman scattering spectroscopy,selective photoreduction},
  language     = {eng},
  number       = {8},
  pages        = {1024--1028},
  publisher    = {John Wiley & Sons},
  series       = {Journal of Raman Spectroscopy},
  title        = {Selective reduction of nitroaromatic compounds on silver nanoparticles by visible light},
  url          = {http://dx.doi.org/10.1002/jrs.3143},
  volume       = {43},
  year         = {2012},
}