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Modeling Ozone Decomposition Flames

Konnov, Alexander LU (2013) In Energy & Fuels 27(1). p.501-506
Abstract
An updated detailed kinetic mechanism for ozone combustion is developed. The contemporary choice of the reaction rate constants is presented with emphasis on their uncertainties. Model predictions are compared with available experimental data for ozone decomposition flames and with the Moscow State University (MSU) mechanism used elsewhere in the literature. These two models show similar performance in calculating laminar burning velocities, yet predict largely different concentration profiles of singlet oxygen, O-2(a(1)triangle g). The necessity for consideration of all reactions included in the mechanism as reversible is emphasized.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Energy & Fuels
volume
27
issue
1
pages
501 - 506
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000317327700058
  • scopus:84872768268
ISSN
0887-0624
DOI
10.1021/ef301621r
language
English
LU publication?
yes
id
311cff2f-3012-4a60-8172-fc5d90e95d8f (old id 3739340)
date added to LUP
2016-04-01 14:32:16
date last changed
2022-02-27 03:06:57
@article{311cff2f-3012-4a60-8172-fc5d90e95d8f,
  abstract     = {{An updated detailed kinetic mechanism for ozone combustion is developed. The contemporary choice of the reaction rate constants is presented with emphasis on their uncertainties. Model predictions are compared with available experimental data for ozone decomposition flames and with the Moscow State University (MSU) mechanism used elsewhere in the literature. These two models show similar performance in calculating laminar burning velocities, yet predict largely different concentration profiles of singlet oxygen, O-2(a(1)triangle g). The necessity for consideration of all reactions included in the mechanism as reversible is emphasized.}},
  author       = {{Konnov, Alexander}},
  issn         = {{0887-0624}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{501--506}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Energy & Fuels}},
  title        = {{Modeling Ozone Decomposition Flames}},
  url          = {{http://dx.doi.org/10.1021/ef301621r}},
  doi          = {{10.1021/ef301621r}},
  volume       = {{27}},
  year         = {{2013}},
}