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Mapping potential energy surfaces by core electron excitation: the resonant Auger decay spectrum of BF3

Miron, C; Feifel, R; Bjorneholm, O; Svensson, S; de Brito, AN; Ristinmaa Sörensen, Stacey LU ; Piancastelli, MN; Simon, M and Morin, P (2002) In Chemical Physics Letters 359(1-2). p.48-54
Abstract
High-resolution electron spectroscopy applied under resonant Auger-Raman conditions is shown to be a powerful tool for characterizing complex potential energy surfaces of core-excited states in polyatomic systems. BF3 is used as a prototype molecule: excitation of the Bls --> 2a(2)(") transition leads to an exceptional out-of-plane vibrational excitation resolved over a wide energy range (3.6 eV). The photon energy dependence of the spectra through the resonance profile is rationalized in the frame of the relative slopes of the potential energy curves along the boron out-of-plane displacement coordinate.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Physics Letters
volume
359
issue
1-2
pages
48 - 54
publisher
Elsevier
external identifiers
  • wos:000176372500008
  • scopus:0037071696
ISSN
0009-2614
DOI
10.1016/S0009-2614(02)00627-9
language
English
LU publication?
yes
id
25ce8b13-3588-4948-8141-9a8156402b67 (old id 335264)
date added to LUP
2007-11-16 13:38:17
date last changed
2017-01-01 06:44:43
@article{25ce8b13-3588-4948-8141-9a8156402b67,
  abstract     = {High-resolution electron spectroscopy applied under resonant Auger-Raman conditions is shown to be a powerful tool for characterizing complex potential energy surfaces of core-excited states in polyatomic systems. BF3 is used as a prototype molecule: excitation of the Bls --> 2a(2)(") transition leads to an exceptional out-of-plane vibrational excitation resolved over a wide energy range (3.6 eV). The photon energy dependence of the spectra through the resonance profile is rationalized in the frame of the relative slopes of the potential energy curves along the boron out-of-plane displacement coordinate.},
  author       = {Miron, C and Feifel, R and Bjorneholm, O and Svensson, S and de Brito, AN and Ristinmaa Sörensen, Stacey and Piancastelli, MN and Simon, M and Morin, P},
  issn         = {0009-2614},
  language     = {eng},
  number       = {1-2},
  pages        = {48--54},
  publisher    = {Elsevier},
  series       = {Chemical Physics Letters},
  title        = {Mapping potential energy surfaces by core electron excitation: the resonant Auger decay spectrum of BF3},
  url          = {http://dx.doi.org/10.1016/S0009-2614(02)00627-9},
  volume       = {359},
  year         = {2002},
}