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Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction

Bjurling, Emelie LU ; Berg, Ulf LU and Andersson, CM (2002) In Organometallics 21(8). p.1583-1590
Abstract
The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
21
issue
8
pages
1583 - 1590
publisher
The American Chemical Society
external identifiers
  • wos:000175025900012
  • scopus:0013219335
ISSN
1520-6041
DOI
10.1021/om011016g
language
English
LU publication?
yes
id
d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e (old id 340179)
date added to LUP
2007-08-10 11:02:50
date last changed
2017-09-10 03:43:27
@article{d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e,
  abstract     = {The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.},
  author       = {Bjurling, Emelie and Berg, Ulf and Andersson, CM},
  issn         = {1520-6041},
  language     = {eng},
  number       = {8},
  pages        = {1583--1590},
  publisher    = {The American Chemical Society},
  series       = {Organometallics},
  title        = {Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction},
  url          = {http://dx.doi.org/10.1021/om011016g},
  volume       = {21},
  year         = {2002},
}