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Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction

Bjurling, Emelie LU ; Berg, Ulf LU and Andersson, CM (2002) In Organometallics 21(8). p.1583-1590
Abstract
The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.
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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
21
issue
8
pages
1583 - 1590
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000175025900012
  • scopus:0013219335
ISSN
1520-6041
DOI
10.1021/om011016g
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e (old id 340179)
date added to LUP
2016-04-01 12:11:52
date last changed
2020-01-12 09:23:49
@article{d0d18f8f-5ee8-4d4a-8c8b-a4e5ccdfc47e,
  abstract     = {The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.},
  author       = {Bjurling, Emelie and Berg, Ulf and Andersson, CM},
  issn         = {1520-6041},
  language     = {eng},
  number       = {8},
  pages        = {1583--1590},
  publisher    = {The American Chemical Society (ACS)},
  series       = {Organometallics},
  title        = {Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction},
  url          = {http://dx.doi.org/10.1021/om011016g},
  doi          = {10.1021/om011016g},
  volume       = {21},
  year         = {2002},
}