Synthesis and crystal structure of Ca2Ag1.83Al 0-67Ge1-50 - A solid solution with the NbCoB-type structure
(2009) In Zeitschrift fur Anorganische und Allgemeine Chemie 635(13-14). p.2143-2146- Abstract
The crystal structure of the new phase, Ca2Ag 1.83Al0.67Ge1.50(1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) Â, b = 4.3807(2) Å c = 7.2211(3) Å, V= 648.65 Å3 (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg2 (or CeCu2) and Fe2P type structures.
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https://lup.lub.lu.se/record/35bd7df5-0225-4718-bdae-0a6f0433d9f8
- author
- Ponou, Simeon LU and Lidin, Sven LU
- publishing date
- 2009-11-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Intergrowth structure, Intermetallic phases, Silver, Solid solution, X-ray diffraction
- in
- Zeitschrift fur Anorganische und Allgemeine Chemie
- volume
- 635
- issue
- 13-14
- pages
- 4 pages
- publisher
- Wiley-Blackwell
- external identifiers
-
- scopus:70449568342
- ISSN
- 0044-2313
- DOI
- 10.1002/zaac.200900156
- language
- English
- LU publication?
- no
- id
- 35bd7df5-0225-4718-bdae-0a6f0433d9f8
- date added to LUP
- 2019-04-08 15:00:52
- date last changed
- 2022-01-31 18:46:44
@article{35bd7df5-0225-4718-bdae-0a6f0433d9f8, abstract = {{<p>The crystal structure of the new phase, Ca<sub>2</sub>Ag <sub>1.83</sub>Al<sub>0.67</sub>Ge<sub>1.50(1)</sub> (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) Â, b = 4.3807(2) Å c = 7.2211(3) Å, V= 648.65 Å<sup>3</sup> (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg<sub>2</sub> (or CeCu<sub>2</sub>) and Fe<sub>2</sub>P type structures.</p>}}, author = {{Ponou, Simeon and Lidin, Sven}}, issn = {{0044-2313}}, keywords = {{Intergrowth structure; Intermetallic phases; Silver; Solid solution; X-ray diffraction}}, language = {{eng}}, month = {{11}}, number = {{13-14}}, pages = {{2143--2146}}, publisher = {{Wiley-Blackwell}}, series = {{Zeitschrift fur Anorganische und Allgemeine Chemie}}, title = {{Synthesis and crystal structure of Ca<sub>2</sub>Ag<sup>1.83</sup>Al <sub>0-67</sub>Ge<sub>1-50</sub> - A solid solution with the NbCoB-type structure}}, url = {{http://dx.doi.org/10.1002/zaac.200900156}}, doi = {{10.1002/zaac.200900156}}, volume = {{635}}, year = {{2009}}, }