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Total Synthesis of Transtaganolide E and F: Insight in the Biosynthesis of the Transtaganolides

Larsson, Rikard LU ; Scheeren, Hans W.; Aben, Rene W. M.; Johansson, Martin H LU and Sterner, Olov LU (2013) In European Journal of Organic Chemistry 2013(30). p.6955-6960
Abstract
A total synthesis of transtaganolide E and F, proposed intermediates in the biosynthesis of the potent transtaganolides, including an Ireland-Claisen rearrangement and a high-pressure intramolecular Diels-Alder cycloaddition reaction of an unactivated 2-pyrone derivative, is reported. The implication of the results to the proposed transtaganolides biosynthesis is discussed.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Transtaganolides, Rearrangement, Cycloaddition, Biosynthesis, Natural, products
in
European Journal of Organic Chemistry
volume
2013
issue
30
pages
6955 - 6960
publisher
John Wiley & Sons
external identifiers
  • wos:000328739500023
  • scopus:84885594044
ISSN
1434-193X
DOI
10.1002/ejoc.201301092
language
English
LU publication?
yes
id
3f60bcec-6bed-4b98-9377-bd4a19d0857b (old id 4272120)
date added to LUP
2014-02-11 14:06:55
date last changed
2019-04-23 01:42:26
@article{3f60bcec-6bed-4b98-9377-bd4a19d0857b,
  abstract     = {A total synthesis of transtaganolide E and F, proposed intermediates in the biosynthesis of the potent transtaganolides, including an Ireland-Claisen rearrangement and a high-pressure intramolecular Diels-Alder cycloaddition reaction of an unactivated 2-pyrone derivative, is reported. The implication of the results to the proposed transtaganolides biosynthesis is discussed.},
  author       = {Larsson, Rikard and Scheeren, Hans W. and Aben, Rene W. M. and Johansson, Martin H and Sterner, Olov},
  issn         = {1434-193X},
  keyword      = {Transtaganolides,Rearrangement,Cycloaddition,Biosynthesis,Natural,products},
  language     = {eng},
  number       = {30},
  pages        = {6955--6960},
  publisher    = {John Wiley & Sons},
  series       = {European Journal of Organic Chemistry},
  title        = {Total Synthesis of Transtaganolide E and F: Insight in the Biosynthesis of the Transtaganolides},
  url          = {http://dx.doi.org/10.1002/ejoc.201301092},
  volume       = {2013},
  year         = {2013},
}