Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate

Abdel-Magied, Ahmed ; Singh, Amrendra LU ; Haukka, Matti and Nordlander, Ebbe LU (2011) In Acta Crystallographica Section E: Structure Reports Online 67(12). p.1601-1816
Abstract
In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
67
issue
12
pages
1601 - 1816
publisher
International Union of Crystallography
external identifiers
  • wos:000298795300129
  • scopus:83155184854
ISSN
1600-5368
DOI
10.1107/S1600536811049312
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
4025bb82-aca3-4a7c-b9ed-ab7d558ea290 (old id 2345073)
date added to LUP
2016-04-01 14:29:41
date last changed
2022-01-28 00:51:57
@article{4025bb82-aca3-4a7c-b9ed-ab7d558ea290,
  abstract     = {{In the title compound, [Re(3)(mu-H)(3)(C(25)H(22)P(2))(CO)(10)]center dot CH(2)Cl(2), the three Re atoms form a triangle bearing ten terminal carbonyl groups and three edge-bridging hydrides. The bis(diphenylphosphanyl) methane ligand bridges two Re atoms. Neglecting the Re-Re interactions, each Re atom is in a slightly distorted octahedral coordination environment. The dichloromethane solvent molecule is disordered over two sets of sites with fixed occupancies of 0.6 and 0.4.}},
  author       = {{Abdel-Magied, Ahmed and Singh, Amrendra and Haukka, Matti and Nordlander, Ebbe}},
  issn         = {{1600-5368}},
  language     = {{eng}},
  number       = {{12}},
  pages        = {{1601--1816}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica Section E: Structure Reports Online}},
  title        = {{[(mu)-Bis(diphenylphosphanyl-kappa P)methane]decacarbonyltri-(mu)-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate}},
  url          = {{http://dx.doi.org/10.1107/S1600536811049312}},
  doi          = {{10.1107/S1600536811049312}},
  volume       = {{67}},
  year         = {{2011}},
}