Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]
(2006) In Inorganic Chemistry Communications 9(7). p.764-766- Abstract
- Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/404537
- author
- Otto, Stefanus ; Roodt, Andreas and Elding, Lars Ivar LU
- organization
- publishing date
- 2006
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- combined UV/vis NMR, bridge-splitting, ethene, platinum(II)
- in
- Inorganic Chemistry Communications
- volume
- 9
- issue
- 7
- pages
- 764 - 766
- publisher
- Elsevier
- external identifiers
-
- wos:000238718300025
- scopus:33744985538
- ISSN
- 1879-0259
- DOI
- 10.1016/j.inoche.2006.04.006
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Inorganic chemistry (ceased) (LUR000010)
- id
- 6554495f-71c2-48a8-86e9-2557c3c75e55 (old id 404537)
- date added to LUP
- 2016-04-01 12:04:15
- date last changed
- 2022-01-26 22:24:00
@article{6554495f-71c2-48a8-86e9-2557c3c75e55, abstract = {{Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.}}, author = {{Otto, Stefanus and Roodt, Andreas and Elding, Lars Ivar}}, issn = {{1879-0259}}, keywords = {{combined UV/vis NMR; bridge-splitting; ethene; platinum(II)}}, language = {{eng}}, number = {{7}}, pages = {{764--766}}, publisher = {{Elsevier}}, series = {{Inorganic Chemistry Communications}}, title = {{Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]}}, url = {{http://dx.doi.org/10.1016/j.inoche.2006.04.006}}, doi = {{10.1016/j.inoche.2006.04.006}}, volume = {{9}}, year = {{2006}}, }