Electron-spectroscopy study of LiC60: Charge transfer and dimer formation
(2000) In Physical Review B (Condensed Matter) 62. p.4253-4253- Abstract
- Li−C60 compounds Lix¯C60 were studied for average Li concentration x¯<~1 using photoelectron spectroscopy. Strong evidence is found for the formation of LiC60 dimers, as well as a second phase. The study suggests that the smallest alkali-metal Li bonds to C60 largely ionically for certain configurations. An investigation of the Li 1s level shows that under certain conditions the energetics favor a backdonation of the transferred electron to the Li ion.
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https://lup.lub.lu.se/record/409dc11c-81bf-40b9-ac9a-595fade87b1a
- author
- Schnadt, Joachim LU ; Brühwiler, Paul A. ; Mårtensson, Nils ; Lassesson, Andreas ; Rohmund, Frank and Campbell, Eleanor E. B.
- organization
- publishing date
- 2000
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review B (Condensed Matter)
- volume
- 62
- pages
- 4253 - 4253
- publisher
- American Physical Society
- ISSN
- 0163-1829
- language
- English
- LU publication?
- yes
- id
- 409dc11c-81bf-40b9-ac9a-595fade87b1a
- date added to LUP
- 2016-04-27 17:22:19
- date last changed
- 2022-02-23 02:16:50
@article{409dc11c-81bf-40b9-ac9a-595fade87b1a, abstract = {{Li−C60 compounds Lix¯C60 were studied for average Li concentration x¯<~1 using photoelectron spectroscopy. Strong evidence is found for the formation of LiC60 dimers, as well as a second phase. The study suggests that the smallest alkali-metal Li bonds to C60 largely ionically for certain configurations. An investigation of the Li 1s level shows that under certain conditions the energetics favor a backdonation of the transferred electron to the Li ion.}}, author = {{Schnadt, Joachim and Brühwiler, Paul A. and Mårtensson, Nils and Lassesson, Andreas and Rohmund, Frank and Campbell, Eleanor E. B.}}, issn = {{0163-1829}}, language = {{eng}}, pages = {{4253--4253}}, publisher = {{American Physical Society}}, series = {{Physical Review B (Condensed Matter)}}, title = {{Electron-spectroscopy study of LiC<sub>60</sub>: Charge transfer and dimer formation}}, url = {{https://lup.lub.lu.se/search/files/7524508/PhysRevB.62.4253.pdf}}, volume = {{62}}, year = {{2000}}, }