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Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2

Wang, Xuefeng ; Roos, Björn LU and Andrews, Lester (2010) In Chemical Communications 46(10). p.1646-1648
Abstract
Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.
Please use this url to cite or link to this publication:
author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Communications
volume
46
issue
10
pages
1646 - 1648
publisher
Royal Society of Chemistry
external identifiers
  • wos:000274827000013
  • scopus:77249157005
  • pmid:20177603
ISSN
1364-548X
DOI
10.1039/b923195a
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Theoretical Chemistry (S) (011001039)
id
442cb472-9505-47ef-902b-b333ff0ad94a (old id 1568306)
date added to LUP
2016-04-01 11:00:22
date last changed
2025-10-14 12:26:06
@article{442cb472-9505-47ef-902b-b333ff0ad94a,
  abstract     = {{Laser-ablated Th atoms react with BF3 during condensation in excess argon at 6 K to form the first actinide borylene (FB=ThF2) and actinide-boron multiple bond. Three new product absorptions in the B-F and Th-F stretching regions of matrix infrared spectra are assigned to FB=ThF2 from comparison to theoretically predicted vibrational frequencies.}},
  author       = {{Wang, Xuefeng and Roos, Björn and Andrews, Lester}},
  issn         = {{1364-548X}},
  language     = {{eng}},
  number       = {{10}},
  pages        = {{1646--1648}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Chemical Communications}},
  title        = {{Matrix infrared spectra and electronic structure calculations of the first actinide borylene: FB=ThF2}},
  url          = {{http://dx.doi.org/10.1039/b923195a}},
  doi          = {{10.1039/b923195a}},
  volume       = {{46}},
  year         = {{2010}},
}