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Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.

Jonasson, Klara LU and Wendt, Ola LU (2014) In Acta Crystallographica Section E: Structure Reports Online 70(Pt 5). p.176-177
Abstract
The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica Section E: Structure Reports Online
volume
70
issue
Pt 5
pages
176 - 177
publisher
Wiley-Blackwell
external identifiers
  • pmid:24860309
  • scopus:84899954551
ISSN
1600-5368
DOI
10.1107/S1600536814007818
language
English
LU publication?
yes
id
39779280-7209-4089-a15b-6af95b613ea1 (old id 4452575)
date added to LUP
2014-06-18 14:47:50
date last changed
2017-04-30 12:42:33
@article{39779280-7209-4089-a15b-6af95b613ea1,
  abstract     = {The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.},
  author       = {Jonasson, Klara and Wendt, Ola},
  issn         = {1600-5368},
  language     = {eng},
  number       = {Pt 5},
  pages        = {176--177},
  publisher    = {Wiley-Blackwell},
  series       = {Acta Crystallographica Section E: Structure Reports Online},
  title        = {Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.},
  url          = {http://dx.doi.org/10.1107/S1600536814007818},
  volume       = {70},
  year         = {2014},
}