Suppression of the molecular ultra-fast dissociation in bromomethane clusters.
(2014) In Journal of Chemical Physics 141(22).- Abstract
- We address the influence of clustering on the ultra-fast dissociation of bromomethane. Valence and core photo-electron spectroscopy, partial electron yield absorption, and resonant Auger spectroscopy have been used together with ab initio calculations to investigate the properties of the ultra-fast dissociation. The ratio of ultra-fast dissociation of molecules in clusters as compared to free molecules is determined to be significantly reduced. We propose partial delocalization of the excited electronic state as being responsible for this behavior.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/4908615
- author
- Rander, T
; Lindblad, A
; Bradeanu, I
; Öhrwall, Gunnar
LU
; Svensson, S and Björneholm, O
- organization
- publishing date
- 2014
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 141
- issue
- 22
- article number
- 224305
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- pmid:25494747
- wos:000346272800023
- scopus:84916227010
- pmid:25494747
- ISSN
- 0021-9606
- DOI
- 10.1063/1.4903455
- language
- English
- LU publication?
- yes
- id
- f3e45cfe-4dcf-416b-968b-6f9e87214e17 (old id 4908615)
- date added to LUP
- 2016-04-01 11:06:57
- date last changed
- 2022-01-26 05:33:13
@article{f3e45cfe-4dcf-416b-968b-6f9e87214e17, abstract = {{We address the influence of clustering on the ultra-fast dissociation of bromomethane. Valence and core photo-electron spectroscopy, partial electron yield absorption, and resonant Auger spectroscopy have been used together with ab initio calculations to investigate the properties of the ultra-fast dissociation. The ratio of ultra-fast dissociation of molecules in clusters as compared to free molecules is determined to be significantly reduced. We propose partial delocalization of the excited electronic state as being responsible for this behavior.}}, author = {{Rander, T and Lindblad, A and Bradeanu, I and Öhrwall, Gunnar and Svensson, S and Björneholm, O}}, issn = {{0021-9606}}, language = {{eng}}, number = {{22}}, publisher = {{American Institute of Physics (AIP)}}, series = {{Journal of Chemical Physics}}, title = {{Suppression of the molecular ultra-fast dissociation in bromomethane clusters.}}, url = {{http://dx.doi.org/10.1063/1.4903455}}, doi = {{10.1063/1.4903455}}, volume = {{141}}, year = {{2014}}, }