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Suppression of the molecular ultra-fast dissociation in bromomethane clusters.

Rander, T; Lindblad, A; Bradeanu, I; Öhrwall, Gunnar LU ; Svensson, S and Björneholm, O (2014) In Journal of Chemical Physics 141(22).
Abstract
We address the influence of clustering on the ultra-fast dissociation of bromomethane. Valence and core photo-electron spectroscopy, partial electron yield absorption, and resonant Auger spectroscopy have been used together with ab initio calculations to investigate the properties of the ultra-fast dissociation. The ratio of ultra-fast dissociation of molecules in clusters as compared to free molecules is determined to be significantly reduced. We propose partial delocalization of the excited electronic state as being responsible for this behavior.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
141
issue
22
publisher
American Institute of Physics
external identifiers
  • pmid:25494747
  • wos:000346272800023
  • scopus:84916227010
ISSN
0021-9606
DOI
10.1063/1.4903455
language
English
LU publication?
yes
id
f3e45cfe-4dcf-416b-968b-6f9e87214e17 (old id 4908615)
date added to LUP
2015-01-12 13:59:00
date last changed
2017-01-01 04:10:34
@article{f3e45cfe-4dcf-416b-968b-6f9e87214e17,
  abstract     = {We address the influence of clustering on the ultra-fast dissociation of bromomethane. Valence and core photo-electron spectroscopy, partial electron yield absorption, and resonant Auger spectroscopy have been used together with ab initio calculations to investigate the properties of the ultra-fast dissociation. The ratio of ultra-fast dissociation of molecules in clusters as compared to free molecules is determined to be significantly reduced. We propose partial delocalization of the excited electronic state as being responsible for this behavior.},
  articleno    = {224305},
  author       = {Rander, T and Lindblad, A and Bradeanu, I and Öhrwall, Gunnar and Svensson, S and Björneholm, O},
  issn         = {0021-9606},
  language     = {eng},
  number       = {22},
  publisher    = {American Institute of Physics},
  series       = {Journal of Chemical Physics},
  title        = {Suppression of the molecular ultra-fast dissociation in bromomethane clusters.},
  url          = {http://dx.doi.org/10.1063/1.4903455},
  volume       = {141},
  year         = {2014},
}