Observation of Pore Growth and Self-Organization in Anodic Alumina by Time-Resolved X-ray Scattering
(2018) In ACS Applied Nano Materials 1(3). p.1265-1271- Abstract
- The anodic oxidation of metals such as aluminum and titanium can lead to the development of self-ordering pores. These pores make excellent templates for a range of nanoscale objects with many applications in nanoscience. Theoretical studies on pore formation have proposed several models for the establishment, growth, and ordering of these pores; however, experimental verification has mostly been limited to ex situ measurements. Here we show that the lateral and vertical pore structure can be probed in situ with high precision, using grazing transmission X-ray scattering. By making use of the high flux available at modern synchrotrons and fitting only the difference between scattering patterns we show the nearly real-time evolution of the... (More)
- The anodic oxidation of metals such as aluminum and titanium can lead to the development of self-ordering pores. These pores make excellent templates for a range of nanoscale objects with many applications in nanoscience. Theoretical studies on pore formation have proposed several models for the establishment, growth, and ordering of these pores; however, experimental verification has mostly been limited to ex situ measurements. Here we show that the lateral and vertical pore structure can be probed in situ with high precision, using grazing transmission X-ray scattering. By making use of the high flux available at modern synchrotrons and fitting only the difference between scattering patterns we show the nearly real-time evolution of the pore’s arrangement. We observe no dependence on the substrate crystallographic orientation for domain size or pore separation. We do however observe an anisotropy in the oxide growth rate for the different substrate surfaces. This experimental approach can be applied to the study of a large variety of electrochemically produced materials such as magnetic nanowires, novel solar cell designs, and catalysts. (Less)
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https://lup.lub.lu.se/record/4d755f37-013b-4486-aa57-609b0b3b260f
- author
- Vinogradov, Nikolay A. LU ; Harlow, Gary S. LU ; Carlà, Francesco ; Evertsson, Jonas LU ; Rullik, Lisa LU ; Linpé, Weronica LU ; Felici, Roberto and Lundgren, Edvin LU
- organization
- publishing date
- 2018
- type
- Contribution to journal
- publication status
- published
- subject
- in
- ACS Applied Nano Materials
- volume
- 1
- issue
- 3
- pages
- 7 pages
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:85047553515
- ISSN
- 2574-0970
- DOI
- 10.1021/acsanm.7b00303
- language
- English
- LU publication?
- yes
- id
- 4d755f37-013b-4486-aa57-609b0b3b260f
- date added to LUP
- 2019-05-08 14:54:09
- date last changed
- 2023-11-18 20:55:46
@article{4d755f37-013b-4486-aa57-609b0b3b260f, abstract = {{The anodic oxidation of metals such as aluminum and titanium can lead to the development of self-ordering pores. These pores make excellent templates for a range of nanoscale objects with many applications in nanoscience. Theoretical studies on pore formation have proposed several models for the establishment, growth, and ordering of these pores; however, experimental verification has mostly been limited to ex situ measurements. Here we show that the lateral and vertical pore structure can be probed in situ with high precision, using grazing transmission X-ray scattering. By making use of the high flux available at modern synchrotrons and fitting only the difference between scattering patterns we show the nearly real-time evolution of the pore’s arrangement. We observe no dependence on the substrate crystallographic orientation for domain size or pore separation. We do however observe an anisotropy in the oxide growth rate for the different substrate surfaces. This experimental approach can be applied to the study of a large variety of electrochemically produced materials such as magnetic nanowires, novel solar cell designs, and catalysts.}}, author = {{Vinogradov, Nikolay A. and Harlow, Gary S. and Carlà, Francesco and Evertsson, Jonas and Rullik, Lisa and Linpé, Weronica and Felici, Roberto and Lundgren, Edvin}}, issn = {{2574-0970}}, language = {{eng}}, number = {{3}}, pages = {{1265--1271}}, publisher = {{The American Chemical Society (ACS)}}, series = {{ACS Applied Nano Materials}}, title = {{Observation of Pore Growth and Self-Organization in Anodic Alumina by Time-Resolved X-ray Scattering}}, url = {{http://dx.doi.org/10.1021/acsanm.7b00303}}, doi = {{10.1021/acsanm.7b00303}}, volume = {{1}}, year = {{2018}}, }