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Thermal Conductivity of Ionic Liquid-Based Nanofluids Containing Magnesium Oxide and Aluminum Oxide Nanoparticles

Hothar, Marcus LU ; Wu, Zan LU and Sundén, Bengt LU (2022) In Heat Transfer Engineering 43(21). p.1806-1819
Abstract

A promising nanomaterial, magnesium oxide (MgO) and a commonly studied nanomaterial, aluminum oxide (Al2O3) were used to enhance the thermal conductivity of two ionic liquids, i.e., 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCa]) and 1-ethyl-3-methylimidazolium tricyanomethanide ([emim][TCM]) of potential as heat transfer medium. Effects of nanoparticle material, size, shape as well as mass concentration on thermal conductivity enhancement were investigated experimentally, along with stability analysis of the nanoparticle suspensions. The thermal conductivity of [emim][TCM] can be enhanced by up to 40% by adding 15 wt.% of polyhedral MgO nanoparticles. The thermal conductivity of Al2O3... (More)

A promising nanomaterial, magnesium oxide (MgO) and a commonly studied nanomaterial, aluminum oxide (Al2O3) were used to enhance the thermal conductivity of two ionic liquids, i.e., 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCa]) and 1-ethyl-3-methylimidazolium tricyanomethanide ([emim][TCM]) of potential as heat transfer medium. Effects of nanoparticle material, size, shape as well as mass concentration on thermal conductivity enhancement were investigated experimentally, along with stability analysis of the nanoparticle suspensions. The thermal conductivity of [emim][TCM] can be enhanced by up to 40% by adding 15 wt.% of polyhedral MgO nanoparticles. The thermal conductivity of Al2O3 ionanofluids does not vary much with nanoparticle size while that of MgO ionanofluids tends to increase as the nanoparticle size decreases. The Maxwell-Garnett model and the Hamilton–Crosser model could estimate the thermal conductivity of [emim][DCa]-based nanofluids containing Al2O3 and MgO nanoparticles, respectively, while under-prediction prevailed for [emim][TCM]-based nanofluids. Besides, challenges were encountered during zeta potential measurements created by the ionic liquids themselves. New methods need to be developed to correctly measure the zeta potential of ionic liquid-based nanofluids.

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author
; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Heat Transfer Engineering
volume
43
issue
21
pages
1806 - 1819
publisher
Taylor & Francis
external identifiers
  • scopus:85121614931
ISSN
0145-7632
DOI
10.1080/01457632.2021.2016133
language
English
LU publication?
yes
id
4e68e3b8-d179-46fb-995f-b3331a46f7e4
date added to LUP
2022-03-23 12:24:20
date last changed
2023-11-16 00:54:45
@article{4e68e3b8-d179-46fb-995f-b3331a46f7e4,
  abstract     = {{<p>A promising nanomaterial, magnesium oxide (MgO) and a commonly studied nanomaterial, aluminum oxide (Al<sub>2</sub>O<sub>3</sub>) were used to enhance the thermal conductivity of two ionic liquids, i.e., 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCa]) and 1-ethyl-3-methylimidazolium tricyanomethanide ([emim][TCM]) of potential as heat transfer medium. Effects of nanoparticle material, size, shape as well as mass concentration on thermal conductivity enhancement were investigated experimentally, along with stability analysis of the nanoparticle suspensions. The thermal conductivity of [emim][TCM] can be enhanced by up to 40% by adding 15 wt.% of polyhedral MgO nanoparticles. The thermal conductivity of Al<sub>2</sub>O<sub>3</sub> ionanofluids does not vary much with nanoparticle size while that of MgO ionanofluids tends to increase as the nanoparticle size decreases. The Maxwell-Garnett model and the Hamilton–Crosser model could estimate the thermal conductivity of [emim][DCa]-based nanofluids containing Al<sub>2</sub>O<sub>3</sub> and MgO nanoparticles, respectively, while under-prediction prevailed for [emim][TCM]-based nanofluids. Besides, challenges were encountered during zeta potential measurements created by the ionic liquids themselves. New methods need to be developed to correctly measure the zeta potential of ionic liquid-based nanofluids.</p>}},
  author       = {{Hothar, Marcus and Wu, Zan and Sundén, Bengt}},
  issn         = {{0145-7632}},
  language     = {{eng}},
  number       = {{21}},
  pages        = {{1806--1819}},
  publisher    = {{Taylor & Francis}},
  series       = {{Heat Transfer Engineering}},
  title        = {{Thermal Conductivity of Ionic Liquid-Based Nanofluids Containing Magnesium Oxide and Aluminum Oxide Nanoparticles}},
  url          = {{http://dx.doi.org/10.1080/01457632.2021.2016133}},
  doi          = {{10.1080/01457632.2021.2016133}},
  volume       = {{43}},
  year         = {{2022}},
}