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Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods

Avdoshenko, S. M. ; Fritz, Fabian ; Schlesier, Christin ; Kostanyan, Aram ; Dreiser, Jan ; Luysberg, Martina ; Popov, Alexey ; Meyer, Carola and Westerström, Rasmus LU (2018) In Nanoscale p.18153-18160
Abstract
The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically... (More)
The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy2ScN@C80 SMMs compared to the bulk analog. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Nanoscale
pages
18153 - 18160
publisher
Royal Society of Chemistry
external identifiers
  • scopus:85054435393
ISSN
2040-3372
DOI
10.1039/C8NR05386C
language
English
LU publication?
yes
id
52b2b02b-85dc-428f-bd23-5128205e1919
date added to LUP
2018-08-29 14:53:45
date last changed
2019-12-10 07:38:45
@article{52b2b02b-85dc-428f-bd23-5128205e1919,
  abstract     = {The magnetic ordering and bistability of one-dimensional chains of endofullerene Dy2ScN@C80 single-molecule magnets (SMMs) packed inside single-walled carbon nanotubes (SWCNTs) have been studied using high-resolution transmission electron microscopy (HRTEM), X-ray magnetic circular dichroism (XMCD), and ab initio calculations. X-ray absorption measurements reveal that the orientation of the encapsulated endofullerenes differs from the isotropic distribution in the bulk sample, indicating a partial ordering of the endofullerenes inside the SWCNTs. The effect of the one-dimensional packing was further investigated by ab initio calculations, demonstrating that for specific tube diameters, the encapsulation is leading to energetically preferential orientations of the endohedral clusters. Additionally, element-specific magnetization curves reveal a decreased magnetic bistability of the encapsulated Dy2ScN@C80 SMMs compared to the bulk analog.},
  author       = {Avdoshenko, S. M. and Fritz, Fabian and Schlesier, Christin and Kostanyan, Aram and Dreiser, Jan  and Luysberg, Martina and Popov, Alexey  and Meyer, Carola  and Westerström, Rasmus},
  issn         = {2040-3372},
  language     = {eng},
  pages        = {18153--18160},
  publisher    = {Royal Society of Chemistry},
  series       = {Nanoscale},
  title        = {Partial magnetic ordering in one-dimensional arrays of endofullerene single-molecule magnet peapods},
  url          = {http://dx.doi.org/10.1039/C8NR05386C},
  doi          = {10.1039/C8NR05386C},
  year         = {2018},
}