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Investigation of lithium and fluorine content in geological materials using Nuclear Reaction Analysis (NRA)

de La Rosa, Nathaly LU (2019)
Abstract
This work focuses on the optimization of the Nuclear Reaction Analysis (NRA) technique to determine the content of lithium and fluorine in geological materials. Measuring low concentration of these isotopes is of great relevance in many fields such as geological, astrophysical, biological and material sciences.

Light elements as lithium and fluorine are considered as geochemical tracers in various geological processes such as the crust-mantle recycling. In these applications, precise measurements are required.

Our interest in geological applications is part of an interdisciplinary collaboration with geologists who provide us with samples and are interested in our results. The development of this project has... (More)
This work focuses on the optimization of the Nuclear Reaction Analysis (NRA) technique to determine the content of lithium and fluorine in geological materials. Measuring low concentration of these isotopes is of great relevance in many fields such as geological, astrophysical, biological and material sciences.

Light elements as lithium and fluorine are considered as geochemical tracers in various geological processes such as the crust-mantle recycling. In these applications, precise measurements are required.

Our interest in geological applications is part of an interdisciplinary collaboration with geologists who provide us with samples and are interested in our results. The development of this project has enabled the Lund Ion Beam Analysis Facility (LIBAF) group to establish a technique for lithium and fluorine measurements that can be used in many fields.

NRA is part of a family of analysis techniques known as Ion Beam Analysis (IBA). The advantages offered by IBA techniques are non-destructiveness, short measurement time, and very good sensitivity over the hole periodic table. Equipment such as particle accelerators and radiation detectors are needed to carry out IBA techniques. These types of equipment have been utilized at the LIBAF in order to perform NRA using Li-bearing and F-bearing materials. In NRA, the samples are scanned by energetic ions such as protons or deuterons to induce reactions with the sample elements. Many reactions
can take place producing charged particles, X-rays and gamma rays. The 7Li(p,α)4He and  19F(p,α)16O reactions were utilized to obtain lithium and fluorine detection limits below 1~ppm and 50~ppm respectively.
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author
supervisor
opponent
  • Dr. Reichart, Patrick, Bundeswehr University Munich, Germany
organization
publishing date
type
Thesis
publication status
published
subject
keywords
Nuclear reaction analysis (NRA), Geological material, Elemental composition analysis, Ion Beam Analysis (IBA)
publisher
Department of Physics, Lund University
defense location
Lecture hall Rydbergssalen, Department of Physics, Professorsgatan 1, Faculty of Engineering LTH, Lund
defense date
2019-11-15 13:15:00
ISBN
978-91-7895-220-5
978-91-7895-219-9
language
English
LU publication?
yes
id
53bedfd9-2242-4d20-91d4-2fde6cb1eb52
date added to LUP
2019-10-21 12:07:39
date last changed
2022-04-27 13:45:15
@phdthesis{53bedfd9-2242-4d20-91d4-2fde6cb1eb52,
  abstract     = {{This work focuses on the optimization of the Nuclear Reaction Analysis (NRA) technique to determine the content of lithium  and fluorine in geological materials. Measuring low concentration of these isotopes is of great relevance in many fields such as geological, astrophysical, biological and material sciences.<br/><br/> Light  elements as lithium and fluorine are considered as geochemical tracers in various geological processes such as  the crust-mantle recycling.  In these applications, precise  measurements are required.<br/><br/>Our interest in geological applications is part  of an interdisciplinary collaboration with geologists  who  provide us with samples and are interested in our results. The development of this project has enabled the Lund Ion Beam Analysis Facility (LIBAF) group to establish a technique for lithium and fluorine measurements that can be used in many fields.<br/><br/>NRA is part of a family of analysis techniques known as Ion Beam Analysis (IBA). The advantages offered by IBA techniques are non-destructiveness, short measurement time, and  very good sensitivity over the hole periodic table.  Equipment such as particle accelerators and radiation detectors are needed to carry out IBA techniques. These types of equipment have been utilized at the LIBAF in order to perform NRA using Li-bearing and F-bearing materials. In NRA, the samples are scanned by energetic ions such as protons or deuterons to induce reactions with the sample elements. Many reactions<br/> can take place producing charged particles, X-rays and gamma rays. The  <sup>7</sup>Li(p,α)<sup>4</sup>He and  <sup>19</sup>F(p,α)<sup>16</sup>O reactions were utilized to obtain lithium  and fluorine detection limits below 1~ppm and 50~ppm respectively.<br/>}},
  author       = {{de La Rosa, Nathaly}},
  isbn         = {{978-91-7895-220-5}},
  keywords     = {{Nuclear reaction analysis (NRA); Geological material; Elemental composition analysis; Ion Beam Analysis (IBA)}},
  language     = {{eng}},
  month        = {{10}},
  publisher    = {{Department of Physics, Lund University}},
  school       = {{Lund University}},
  title        = {{Investigation of lithium and fluorine content in geological materials using  Nuclear Reaction Analysis (NRA)}},
  url          = {{https://lup.lub.lu.se/search/files/70842884/InvestigationOfLithiumAndFluorineContentInGeologicalMaterialsUsingNuclearReactionAnalysis_NRA_.pdf}},
  year         = {{2019}},
}