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Lone-pair interfaces that divide inorganic materials into ionic and covalent parts

Mayerová, Zuzana ; Johnsson, Mats LU and Lidin, Sven LU (2006) In Angewandte Chemie - International Edition 45(34). p.5602-5606
Abstract

The lone (ar)ranger: The structure of Cu20Sb35O 44Cl37 is divided up into two parts: ionically bonded Cu+-Cl- supertetrahedra (green) and covalently bonded clusters that resemble zeolite β cages. The Sb3+ ions (gray) lie at the vertices of the cages, while their lone pairs of electrons form surfaces that separate the covalent and ionic parts. (Figure Presented).

Please use this url to cite or link to this publication:
author
; and
publishing date
type
Contribution to journal
publication status
published
keywords
Antimony, Cluster compounds, Halides, Interfaces, Structure elucidation
in
Angewandte Chemie - International Edition
volume
45
issue
34
pages
5 pages
publisher
John Wiley & Sons Inc.
external identifiers
  • scopus:33748567851
ISSN
1433-7851
DOI
10.1002/anie.200600861
language
English
LU publication?
no
id
5f418226-94a9-4c33-b469-77f8c68d4a51
date added to LUP
2019-04-08 15:18:48
date last changed
2022-02-15 17:53:50
@article{5f418226-94a9-4c33-b469-77f8c68d4a51,
  abstract     = {{<p>The lone (ar)ranger: The structure of Cu<sub>20</sub>Sb<sub>35</sub>O <sub>44</sub>Cl<sub>37</sub> is divided up into two parts: ionically bonded Cu<sup>+</sup>-Cl<sup>-</sup> supertetrahedra (green) and covalently bonded clusters that resemble zeolite β cages. The Sb<sup>3+</sup> ions (gray) lie at the vertices of the cages, while their lone pairs of electrons form surfaces that separate the covalent and ionic parts. (Figure Presented).</p>}},
  author       = {{Mayerová, Zuzana and Johnsson, Mats and Lidin, Sven}},
  issn         = {{1433-7851}},
  keywords     = {{Antimony; Cluster compounds; Halides; Interfaces; Structure elucidation}},
  language     = {{eng}},
  month        = {{09}},
  number       = {{34}},
  pages        = {{5602--5606}},
  publisher    = {{John Wiley & Sons Inc.}},
  series       = {{Angewandte Chemie - International Edition}},
  title        = {{Lone-pair interfaces that divide inorganic materials into ionic and covalent parts}},
  url          = {{http://dx.doi.org/10.1002/anie.200600861}},
  doi          = {{10.1002/anie.200600861}},
  volume       = {{45}},
  year         = {{2006}},
}