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Lone-pair interfaces that divide inorganic materials into ionic and covalent parts

Mayerová, Zuzana ; Johnsson, Mats LU and Lidin, Sven LU (2006) In Angewandte Chemie - International Edition 45(34). p.5602-5606
Abstract

The lone (ar)ranger: The structure of Cu20Sb35O 44Cl37 is divided up into two parts: ionically bonded Cu+-Cl- supertetrahedra (green) and covalently bonded clusters that resemble zeolite β cages. The Sb3+ ions (gray) lie at the vertices of the cages, while their lone pairs of electrons form surfaces that separate the covalent and ionic parts. (Figure Presented).

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author
publishing date
type
Contribution to journal
publication status
published
keywords
Antimony, Cluster compounds, Halides, Interfaces, Structure elucidation
in
Angewandte Chemie - International Edition
volume
45
issue
34
pages
5 pages
publisher
John Wiley & Sons
external identifiers
  • scopus:33748567851
ISSN
1433-7851
DOI
10.1002/anie.200600861
language
English
LU publication?
no
id
5f418226-94a9-4c33-b469-77f8c68d4a51
date added to LUP
2019-04-08 15:18:48
date last changed
2020-01-13 01:37:57
@article{5f418226-94a9-4c33-b469-77f8c68d4a51,
  abstract     = {<p>The lone (ar)ranger: The structure of Cu<sub>20</sub>Sb<sub>35</sub>O <sub>44</sub>Cl<sub>37</sub> is divided up into two parts: ionically bonded Cu<sup>+</sup>-Cl<sup>-</sup> supertetrahedra (green) and covalently bonded clusters that resemble zeolite β cages. The Sb<sup>3+</sup> ions (gray) lie at the vertices of the cages, while their lone pairs of electrons form surfaces that separate the covalent and ionic parts. (Figure Presented).</p>},
  author       = {Mayerová, Zuzana and Johnsson, Mats and Lidin, Sven},
  issn         = {1433-7851},
  language     = {eng},
  month        = {09},
  number       = {34},
  pages        = {5602--5606},
  publisher    = {John Wiley & Sons},
  series       = {Angewandte Chemie - International Edition},
  title        = {Lone-pair interfaces that divide inorganic materials into ionic and covalent parts},
  url          = {http://dx.doi.org/10.1002/anie.200600861},
  doi          = {10.1002/anie.200600861},
  volume       = {45},
  year         = {2006},
}