Acetate formation during the ethanol oxidation on Rh(1 1 1)
(2006) In Surface Science 600(24). p.5136-5141- Abstract
- The catalytic cracking of ethanol on clean and oxygen precovered Rh(1 1 1) surfaces has been studied by a combination of synchrotron based high-resolution core level spectroscopy and surface infrared spectroscopy. On the clean surface the decomposition of ethanol occurs without any formation of atomic oxygen. The presence of oxygen on the surface changes the reactivity significantly and previous termacetatenext term (CH3COO) was identified as an important surface intermediate in the ethanol oxidation.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/634074
- author
- Resta, Andrea LU ; Blomquist, Jakob LU ; Gustafson, Johan LU ; Karhu, H. ; Mikkelsen, Anders LU ; Lundgren, Edvin LU ; Uvdal, Per LU and Andersen, Jesper N LU
- organization
- publishing date
- 2006
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Surface Science
- volume
- 600
- issue
- 24
- pages
- 5136 - 5141
- publisher
- Elsevier
- external identifiers
-
- wos:000243248100008
- scopus:33845200534
- ISSN
- 0039-6028
- DOI
- 10.1016/j.susc.2006.08.039
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Synchrotron Radiation Research (011013009), Inorganic chemistry (ceased) (LUR000010), Chemical Physics (S) (011001060)
- id
- fefd10f4-e5a6-41ca-8aed-608f94f35bf1 (old id 634074)
- date added to LUP
- 2016-04-01 15:35:10
- date last changed
- 2022-01-28 06:05:36
@article{fefd10f4-e5a6-41ca-8aed-608f94f35bf1, abstract = {{The catalytic cracking of ethanol on clean and oxygen precovered Rh(1 1 1) surfaces has been studied by a combination of synchrotron based high-resolution core level spectroscopy and surface infrared spectroscopy. On the clean surface the decomposition of ethanol occurs without any formation of atomic oxygen. The presence of oxygen on the surface changes the reactivity significantly and previous termacetatenext term (CH3COO) was identified as an important surface intermediate in the ethanol oxidation.}}, author = {{Resta, Andrea and Blomquist, Jakob and Gustafson, Johan and Karhu, H. and Mikkelsen, Anders and Lundgren, Edvin and Uvdal, Per and Andersen, Jesper N}}, issn = {{0039-6028}}, language = {{eng}}, number = {{24}}, pages = {{5136--5141}}, publisher = {{Elsevier}}, series = {{Surface Science}}, title = {{Acetate formation during the ethanol oxidation on Rh(1 1 1)}}, url = {{http://dx.doi.org/10.1016/j.susc.2006.08.039}}, doi = {{10.1016/j.susc.2006.08.039}}, volume = {{600}}, year = {{2006}}, }