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Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]

Otto, Stefanus; Roodt, Andreas and Elding, Lars Ivar LU (2006) In Inorganic Chemistry Communications 9(7). p.764-766
Abstract
Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
combined UV/vis NMR, bridge-splitting, ethene, platinum(II)
in
Inorganic Chemistry Communications
volume
9
issue
7
pages
764 - 766
publisher
Elsevier
external identifiers
  • wos:000238718300025
  • scopus:33744985538
ISSN
1879-0259
DOI
10.1016/j.inoche.2006.04.006
language
English
LU publication?
yes
id
6554495f-71c2-48a8-86e9-2557c3c75e55 (old id 404537)
date added to LUP
2007-10-13 16:18:21
date last changed
2019-02-20 04:11:17
@article{6554495f-71c2-48a8-86e9-2557c3c75e55,
  abstract     = {Bridge splitting of trans- [PtCl2(C2H4)](2) by C2H4 in chloroform yields trans-[PtCl2(C2H4)(2)] which slowly isomerises to cis[PtCl2(C2H4)(2)] (crystal structure reported); the bridge-splitting equilibrium constant was determined as 6.8 +/- 0.6 mol(-1) dm(3) by the use of a combined NMR tube/spectrophotometric cell, enabling NMR and UV/vis measurements on the same closed system. (C) 2006 Elsevier B.V. All rights reserved.},
  author       = {Otto, Stefanus and Roodt, Andreas and Elding, Lars Ivar},
  issn         = {1879-0259},
  keyword      = {combined UV/vis NMR,bridge-splitting,ethene,platinum(II)},
  language     = {eng},
  number       = {7},
  pages        = {764--766},
  publisher    = {Elsevier},
  series       = {Inorganic Chemistry Communications},
  title        = {Bridge splitting of trans-[PtCl2(C2H4)](2) by ethene using a simple combined NMR-UV/vis cell: Crystal and molecular structure of cis-[PtCl2(C2H4)(2)]},
  url          = {http://dx.doi.org/10.1016/j.inoche.2006.04.006},
  volume       = {9},
  year         = {2006},
}