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Iridium complexes with aliphatic, non-innocent pincer ligands

Polukeev, Alexey V. LU and Wendt, Ola F. LU (2018) In Journal of Organometallic Chemistry 867. p.33-50
Abstract

Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PCsp3P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.

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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Catalysis, Iridium, Metal-ligand cooperation, Non-innocent ligands, Pincer complexes
in
Journal of Organometallic Chemistry
volume
867
pages
33 - 50
publisher
Elsevier
external identifiers
  • scopus:85038819939
ISSN
0022-328X
DOI
10.1016/j.jorganchem.2017.12.009
language
English
LU publication?
yes
id
6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60
date added to LUP
2018-01-04 13:37:53
date last changed
2022-03-17 03:26:24
@article{6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60,
  abstract     = {{<p>Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PC<sub>sp3</sub>P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.</p>}},
  author       = {{Polukeev, Alexey V. and Wendt, Ola F.}},
  issn         = {{0022-328X}},
  keywords     = {{Catalysis; Iridium; Metal-ligand cooperation; Non-innocent ligands; Pincer complexes}},
  language     = {{eng}},
  pages        = {{33--50}},
  publisher    = {{Elsevier}},
  series       = {{Journal of Organometallic Chemistry}},
  title        = {{Iridium complexes with aliphatic, non-innocent pincer ligands}},
  url          = {{http://dx.doi.org/10.1016/j.jorganchem.2017.12.009}},
  doi          = {{10.1016/j.jorganchem.2017.12.009}},
  volume       = {{867}},
  year         = {{2018}},
}