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Iridium complexes with aliphatic, non-innocent pincer ligands

Polukeev, Alexey V. LU and Wendt, Ola F. LU (2017) In Journal of Organometallic Chemistry
Abstract

Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PCsp3P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.

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author
organization
publishing date
type
Contribution to journal
publication status
epub
subject
keywords
Catalysis, Iridium, Metal-ligand cooperation, Non-innocent ligands, Pincer complexes
in
Journal of Organometallic Chemistry
publisher
Elsevier
external identifiers
  • scopus:85038819939
ISSN
0022-328X
DOI
10.1016/j.jorganchem.2017.12.009
language
English
LU publication?
yes
id
6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60
date added to LUP
2018-01-04 13:37:53
date last changed
2018-01-04 13:37:53
@article{6e76388b-07bc-4a6a-8d4a-1b7af4aa0a60,
  abstract     = {<p>Pincer complexes attract considerable attention both as interesting objects for fundamental studies and efficient catalysts. This review describes a relatively new offshoot of the field - namely, the chemistry of iridium complexes with aliphatic PC<sub>sp3</sub>P non-innocent pincer ligands. High flexibility, often combined with possibility to activate internal C-H bonds, offers several new patterns of metal-ligand cooperation; some of them were successfully used in catalysis of acceptorless alcohol dehydrogenation, olefin hydroformylation and deuterium exchange, others opened up for remarkable stoichiometric reactions.</p>},
  author       = {Polukeev, Alexey V. and Wendt, Ola F.},
  issn         = {0022-328X},
  keyword      = {Catalysis,Iridium,Metal-ligand cooperation,Non-innocent ligands,Pincer complexes},
  language     = {eng},
  month        = {12},
  publisher    = {Elsevier},
  series       = {Journal of Organometallic Chemistry},
  title        = {Iridium complexes with aliphatic, non-innocent pincer ligands},
  url          = {http://dx.doi.org/10.1016/j.jorganchem.2017.12.009},
  year         = {2017},
}