A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system.
(2016) In Physical chemistry chemical physics : PCCP 18(5). p.3910-3920- Abstract
- New insights into the reaction pathways of different potassium/magnesium amide-hydride based systems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K-N-H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide-hydride anionic exchange is proposed.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/8589177
- author
- organization
- publishing date
- 2016
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical chemistry chemical physics : PCCP
- volume
- 18
- issue
- 5
- pages
- 3910 - 3920
- publisher
- Royal Society of Chemistry
- external identifiers
-
- pmid:26765796
- wos:000369508100064
- pmid:26765796
- scopus:84979960642
- ISSN
- 1463-9084
- DOI
- 10.1039/c5cp06963g
- language
- English
- LU publication?
- yes
- id
- 8d8499fb-b4ec-4939-8f54-0d5fd3d57284 (old id 8589177)
- date added to LUP
- 2016-04-01 13:51:02
- date last changed
- 2022-03-29 17:49:41
@article{8d8499fb-b4ec-4939-8f54-0d5fd3d57284, abstract = {{New insights into the reaction pathways of different potassium/magnesium amide-hydride based systems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K-N-H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide-hydride anionic exchange is proposed.}}, author = {{Santoru, A and Garroni, S and Pistidda, C and Milanese, C and Girella, A and Marini, A and Masolo, E and Valentoni, A and Bergemann, N and Le, T T and Cao, H and Haase, Dörthe and Balmes, Olivier and Taube, K and Mulas, G and Enzo, S and Klassen, T and Dornheim, M}}, issn = {{1463-9084}}, language = {{eng}}, number = {{5}}, pages = {{3910--3920}}, publisher = {{Royal Society of Chemistry}}, series = {{Physical chemistry chemical physics : PCCP}}, title = {{A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system.}}, url = {{http://dx.doi.org/10.1039/c5cp06963g}}, doi = {{10.1039/c5cp06963g}}, volume = {{18}}, year = {{2016}}, }