Advanced

A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system.

Santoru, A; Garroni, S; Pistidda, C; Milanese, C; Girella, A; Marini, A; Masolo, E; Valentoni, A; Bergemann, N and Le, T T, et al. (2016) In Physical chemistry chemical physics : PCCP 18(5). p.3910-3920
Abstract
New insights into the reaction pathways of different potassium/magnesium amide-hydride based systems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K-N-H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide-hydride anionic exchange is proposed.
Please use this url to cite or link to this publication:
author
, et al. (More)
(Less)
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physical chemistry chemical physics : PCCP
volume
18
issue
5
pages
3910 - 3920
publisher
Royal Society of Chemistry
external identifiers
  • pmid:26765796
  • wos:000369508100064
  • scopus:84979960642
ISSN
1463-9084
DOI
10.1039/c5cp06963g
language
English
LU publication?
yes
id
8d8499fb-b4ec-4939-8f54-0d5fd3d57284 (old id 8589177)
date added to LUP
2016-02-11 21:59:15
date last changed
2017-01-01 05:54:49
@article{8d8499fb-b4ec-4939-8f54-0d5fd3d57284,
  abstract     = {New insights into the reaction pathways of different potassium/magnesium amide-hydride based systems are discussed. In situ SR-PXD experiments were for the first time performed in order to reveal the evolution of the phases connected with the hydrogen releasing processes. Evidence of a new K-N-H intermediate is shown and discussed with particular focus on structural modification. Based on these results, a new reaction mechanism of amide-hydride anionic exchange is proposed.},
  author       = {Santoru, A and Garroni, S and Pistidda, C and Milanese, C and Girella, A and Marini, A and Masolo, E and Valentoni, A and Bergemann, N and Le, T T and Cao, H and Haase, Dörthe and Balmes, Olivier and Taube, K and Mulas, G and Enzo, S and Klassen, T and Dornheim, M},
  issn         = {1463-9084},
  language     = {eng},
  number       = {5},
  pages        = {3910--3920},
  publisher    = {Royal Society of Chemistry},
  series       = {Physical chemistry chemical physics : PCCP},
  title        = {A new potassium-based intermediate and its role in the desorption properties of the K-Mg-N-H system.},
  url          = {http://dx.doi.org/10.1039/c5cp06963g},
  volume       = {18},
  year         = {2016},
}