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Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands

Kondrashov, Mikhail LU ; Gritcenko, Roman; Fleckhaus, André LU and Wendt, Ola LU (2016) In Inorganica Chimica Acta 443. p.136-140
Abstract
The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium, Bidentate ligands, Bridging ligands, C-H activation
in
Inorganica Chimica Acta
volume
443
pages
136 - 140
publisher
Elsevier
external identifiers
  • wos:000369070900019
  • scopus:84953911213
ISSN
0020-1693
DOI
10.1016/j.ica.2015.12.032
language
English
LU publication?
yes
id
dac125e1-d8cd-4d37-9f96-db728aad61e4 (old id 8728510)
date added to LUP
2016-02-26 10:42:45
date last changed
2017-01-01 05:23:09
@article{dac125e1-d8cd-4d37-9f96-db728aad61e4,
  abstract     = {The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.},
  author       = {Kondrashov, Mikhail and Gritcenko, Roman and Fleckhaus, André and Wendt, Ola},
  issn         = {0020-1693},
  keyword      = {Palladium,Bidentate ligands,Bridging ligands,C-H activation},
  language     = {eng},
  pages        = {136--140},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands},
  url          = {http://dx.doi.org/10.1016/j.ica.2015.12.032},
  volume       = {443},
  year         = {2016},
}