Pd2Cd11-delta (0.21
(2013) In Journal of Solid State Chemistry 201. p.244-249- Abstract
- The Cd rich part of the Cd-Pd phase diagram was reassessed by means of synthesis and single crystal and powder X-ray diffraction. The region contains two phases that have been reported to have substantial compositional widths, Cd11Pd2 and Cd4Pd. The phase Cd11Pd2 that has previously been reported to be a disordered gamma-brass crystallizing is space group P (4) over bar 3m is here shown to crystallize in I (4) over bar 3m and the mechanism for compositional variation is explained. The phase Pd4Cd has previously been shown to constitute a phase field or a phase bundle of modulated structures and here we determine the structure of a compound Pd0.238Cd0.762 which crystallizes in the orthorhombic superspace group Fmmm(alpha 00)0s0 (F=[(1/2,... (More)
- The Cd rich part of the Cd-Pd phase diagram was reassessed by means of synthesis and single crystal and powder X-ray diffraction. The region contains two phases that have been reported to have substantial compositional widths, Cd11Pd2 and Cd4Pd. The phase Cd11Pd2 that has previously been reported to be a disordered gamma-brass crystallizing is space group P (4) over bar 3m is here shown to crystallize in I (4) over bar 3m and the mechanism for compositional variation is explained. The phase Pd4Cd has previously been shown to constitute a phase field or a phase bundle of modulated structures and here we determine the structure of a compound Pd0.238Cd0.762 which crystallizes in the orthorhombic superspace group Fmmm(alpha 00)0s0 (F=[(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the fundamental cell dimensions a=4.687(2) angstrom, b=10.000(1) angstrom, c=14.140(2) angstrom, q=0.6432(6)a*. (C) 2013 Elsevier Inc. All rights reserved. (Less)
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- author
- Jana, Partha LU and Lidin, Sven LU
- organization
- publishing date
- 2013
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Intermetallic phases, Palladium, Cadmium, gamma-brass phase, Incommensurate phase, X-ray diffraction
- in
- Journal of Solid State Chemistry
- volume
- 201
- pages
- 244 - 249
- publisher
- Elsevier
- external identifiers
-
- wos:000318136600036
- scopus:84875322324
- ISSN
- 0022-4596
- DOI
- 10.1016/j.jssc.2013.01.044
- language
- English
- LU publication?
- yes
- id
- 8cccfa92-f0e4-40f8-ab93-a56ec9ab4b4a (old id 3821476)
- date added to LUP
- 2016-04-01 13:14:03
- date last changed
- 2022-04-13 23:57:18
@article{8cccfa92-f0e4-40f8-ab93-a56ec9ab4b4a,
abstract = {{The Cd rich part of the Cd-Pd phase diagram was reassessed by means of synthesis and single crystal and powder X-ray diffraction. The region contains two phases that have been reported to have substantial compositional widths, Cd11Pd2 and Cd4Pd. The phase Cd11Pd2 that has previously been reported to be a disordered gamma-brass crystallizing is space group P (4) over bar 3m is here shown to crystallize in I (4) over bar 3m and the mechanism for compositional variation is explained. The phase Pd4Cd has previously been shown to constitute a phase field or a phase bundle of modulated structures and here we determine the structure of a compound Pd0.238Cd0.762 which crystallizes in the orthorhombic superspace group Fmmm(alpha 00)0s0 (F=[(1/2, 1/2, 0, 0); (1/2, 0, 1/2, 0); (0, 1/2, 1/2, 0)] with the fundamental cell dimensions a=4.687(2) angstrom, b=10.000(1) angstrom, c=14.140(2) angstrom, q=0.6432(6)a*. (C) 2013 Elsevier Inc. All rights reserved.}},
author = {{Jana, Partha and Lidin, Sven}},
issn = {{0022-4596}},
keywords = {{Intermetallic phases; Palladium; Cadmium; gamma-brass phase; Incommensurate phase; X-ray diffraction}},
language = {{eng}},
pages = {{244--249}},
publisher = {{Elsevier}},
series = {{Journal of Solid State Chemistry}},
title = {{Pd2Cd11-delta (0.21}},
url = {{http://dx.doi.org/10.1016/j.jssc.2013.01.044}},
doi = {{10.1016/j.jssc.2013.01.044}},
volume = {{201}},
year = {{2013}},
}