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Fracture characteristics of acetylated young Scots pine

Forsman, Karin LU ; Serrano, Erik LU orcid ; Danielsson, Henrik LU orcid and Engqvist, Jonas LU (2020) In European Journal of Wood and Wood Products 78(4). p.693-703
Abstract

A study on the fracture characteristics of unmodified and chemically modified Scots pine (Pinus sylvestris) is presented. The investigated material consisted of small-dimension sawn timber originating from young logs (thinnings), aged 30–40 years. The modified samples were acetylated with acetic anhydride in an industrial scale process without the use of any catalyst, reaching an acetyl content of approximately 20%. Clear wood specimens, consisting of either heartwood or sapwood, were extracted and conditioned to equilibrium at a relative humidity of 60% and a temperature of 20 °C. The fracture energy for mode I loading in tension perpendicular to the grain was determined using single edge notched beam (SENB) specimens, subjected to... (More)

A study on the fracture characteristics of unmodified and chemically modified Scots pine (Pinus sylvestris) is presented. The investigated material consisted of small-dimension sawn timber originating from young logs (thinnings), aged 30–40 years. The modified samples were acetylated with acetic anhydride in an industrial scale process without the use of any catalyst, reaching an acetyl content of approximately 20%. Clear wood specimens, consisting of either heartwood or sapwood, were extracted and conditioned to equilibrium at a relative humidity of 60% and a temperature of 20 °C. The fracture energy for mode I loading in tension perpendicular to the grain was determined using single edge notched beam (SENB) specimens, subjected to three-point bending. Additionally, the modulus of elasticity along the grain and the tensile strength perpendicular to the grain were determined for sapwood specimens. The findings demonstrated a significant decrease (between 36 and 50%) in the fracture energy for the acetylated specimens, compared to the unmodified specimens. No significant effect of the acetylation process on the modulus of elasticity, nor on the tensile strength could be concluded. This study indicates that the acetylation process used results in an increased brittleness for Scots pine. Further studies are needed to analyse why the fracture energy is impaired, and to examine whether and how current timber engineering design provisions can or should be revised to account for the increased brittleness of acetylated Scots pine.

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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
European Journal of Wood and Wood Products
volume
78
issue
4
pages
11 pages
publisher
Springer
external identifiers
  • scopus:85086706207
ISSN
0018-3768
DOI
10.1007/s00107-020-01548-3
project
Modifierat trä för utomhuskonstruktioner
Bärande utomhusträ
language
English
LU publication?
yes
id
9b07e0e7-53ca-4137-b6da-070e9cf025e3
date added to LUP
2020-07-10 11:43:51
date last changed
2022-05-12 03:42:26
@article{9b07e0e7-53ca-4137-b6da-070e9cf025e3,
  abstract     = {{<p>A study on the fracture characteristics of unmodified and chemically modified Scots pine (Pinus sylvestris) is presented. The investigated material consisted of small-dimension sawn timber originating from young logs (thinnings), aged 30–40 years. The modified samples were acetylated with acetic anhydride in an industrial scale process without the use of any catalyst, reaching an acetyl content of approximately 20%. Clear wood specimens, consisting of either heartwood or sapwood, were extracted and conditioned to equilibrium at a relative humidity of 60% and a temperature of 20 °C. The fracture energy for mode I loading in tension perpendicular to the grain was determined using single edge notched beam (SENB) specimens, subjected to three-point bending. Additionally, the modulus of elasticity along the grain and the tensile strength perpendicular to the grain were determined for sapwood specimens. The findings demonstrated a significant decrease (between 36 and 50%) in the fracture energy for the acetylated specimens, compared to the unmodified specimens. No significant effect of the acetylation process on the modulus of elasticity, nor on the tensile strength could be concluded. This study indicates that the acetylation process used results in an increased brittleness for Scots pine. Further studies are needed to analyse why the fracture energy is impaired, and to examine whether and how current timber engineering design provisions can or should be revised to account for the increased brittleness of acetylated Scots pine.</p>}},
  author       = {{Forsman, Karin and Serrano, Erik and Danielsson, Henrik and Engqvist, Jonas}},
  issn         = {{0018-3768}},
  language     = {{eng}},
  number       = {{4}},
  pages        = {{693--703}},
  publisher    = {{Springer}},
  series       = {{European Journal of Wood and Wood Products}},
  title        = {{Fracture characteristics of acetylated young Scots pine}},
  url          = {{http://dx.doi.org/10.1007/s00107-020-01548-3}},
  doi          = {{10.1007/s00107-020-01548-3}},
  volume       = {{78}},
  year         = {{2020}},
}