The effect of first-stage polymer Tg on the morphology and thermomechanical properties of structured polymer latex particles
(2003) In Comptes Rendus. Chimie 6(11-12). p.1233-1244- Abstract
- A series of heterogeneous latexes having stage ratios of 40:60 between the first and second stage polymers were prepared by emulsion polymerization. The first-stage polymers were non-polar S-BuA with Tgs ranging from + 100 °C to + 20 °C and the second stage polymer was polar MMA–BuA–MAA having a Tg of 20 °C. The latex particle morphologies were studied using TEM and the thermomechanical properties of the resulting latex films were studied with DSC and DMA. Calculated diffusion rates for propagating species during the reactions were correlated to the observed morphologies and to the amount of interphase in the latex particles.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/129528
- author
- Karlsson, Ola LU ; Hassander, Helen LU and Colombini, Didier LU
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Comptes Rendus. Chimie
- volume
- 6
- issue
- 11-12
- pages
- 1233 - 1244
- publisher
- Elsevier
- external identifiers
-
- wos:000187639500003
- scopus:0344665735
- ISSN
- 1631-0748
- DOI
- 10.1016/j.crci.2003.07.012
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041), Department of Chemistry (011001220)
- id
- a1a5994b-4124-4fd8-9d1d-8dcb32882545 (old id 129528)
- date added to LUP
- 2016-04-01 12:12:32
- date last changed
- 2022-01-27 00:27:24
@article{a1a5994b-4124-4fd8-9d1d-8dcb32882545, abstract = {{A series of heterogeneous latexes having stage ratios of 40:60 between the first and second stage polymers were prepared by emulsion polymerization. The first-stage polymers were non-polar S-BuA with Tgs ranging from + 100 °C to + 20 °C and the second stage polymer was polar MMA–BuA–MAA having a Tg of 20 °C. The latex particle morphologies were studied using TEM and the thermomechanical properties of the resulting latex films were studied with DSC and DMA. Calculated diffusion rates for propagating species during the reactions were correlated to the observed morphologies and to the amount of interphase in the latex particles.}}, author = {{Karlsson, Ola and Hassander, Helen and Colombini, Didier}}, issn = {{1631-0748}}, language = {{eng}}, number = {{11-12}}, pages = {{1233--1244}}, publisher = {{Elsevier}}, series = {{Comptes Rendus. Chimie}}, title = {{The effect of first-stage polymer Tg on the morphology and thermomechanical properties of structured polymer latex particles}}, url = {{http://dx.doi.org/10.1016/j.crci.2003.07.012}}, doi = {{10.1016/j.crci.2003.07.012}}, volume = {{6}}, year = {{2003}}, }