Iron Photoredox Catalysis-Past, Present, and Future
de Groot, Lisa H.M. LU ; Ilic, Aleksandra LU
; Schwarz, Jesper
LU
and Wärnmark, Kenneth
LU
(2023)
In Journal of the American Chemical Society
145(17).
p.9369-9388
- Abstract
Photoredox catalysis of organic reactions driven by iron has attracted substantial attention throughout recent years, due to potential environmental and economic benefits. In this Perspective, three major strategies were identified that have been employed to date to achieve reactivities comparable to the successful noble metal photoredox catalysis: (1) Direct replacement of a noble metal center by iron in archetypal polypyridyl complexes, resulting in a metal-centered photofunctional state. (2) In situ generation of photoactive complexes by substrate coordination where the reactions are driven via intramolecular electron transfer involving charge-transfer states, for example, through visible-light-induced homolysis. (3) Improving the... (More)
Photoredox catalysis of organic reactions driven by iron has attracted substantial attention throughout recent years, due to potential environmental and economic benefits. In this Perspective, three major strategies were identified that have been employed to date to achieve reactivities comparable to the successful noble metal photoredox catalysis: (1) Direct replacement of a noble metal center by iron in archetypal polypyridyl complexes, resulting in a metal-centered photofunctional state. (2) In situ generation of photoactive complexes by substrate coordination where the reactions are driven via intramolecular electron transfer involving charge-transfer states, for example, through visible-light-induced homolysis. (3) Improving the excited-state lifetimes and redox potentials of the charge-transfer states of iron complexes through new ligand design. We seek to give an overview and evaluation of recent developments in this rapidly growing field and, at the same time, provide an outlook on the future of iron-based photoredox catalysis.
(Less)
- author
- de Groot, Lisa H.M.
LU
; Ilic, Aleksandra
LU
; Schwarz, Jesper
LU
and Wärnmark, Kenneth
LU
- organization
- publishing date
- 2023
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of the American Chemical Society
- volume
- 145
- issue
- 17
- pages
- 20 pages
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- pmid:37079887
- scopus:85153965995
- ISSN
- 0002-7863
- DOI
- 10.1021/jacs.3c01000
- language
- English
- LU publication?
- yes
- id
- a55e4af9-03b4-4b87-947a-1300ee71c8a5
- date added to LUP
- 2023-07-14 13:35:32
- date last changed
- 2024-04-20 00:33:32
@article{a55e4af9-03b4-4b87-947a-1300ee71c8a5,
abstract = {{<p>Photoredox catalysis of organic reactions driven by iron has attracted substantial attention throughout recent years, due to potential environmental and economic benefits. In this Perspective, three major strategies were identified that have been employed to date to achieve reactivities comparable to the successful noble metal photoredox catalysis: (1) Direct replacement of a noble metal center by iron in archetypal polypyridyl complexes, resulting in a metal-centered photofunctional state. (2) In situ generation of photoactive complexes by substrate coordination where the reactions are driven via intramolecular electron transfer involving charge-transfer states, for example, through visible-light-induced homolysis. (3) Improving the excited-state lifetimes and redox potentials of the charge-transfer states of iron complexes through new ligand design. We seek to give an overview and evaluation of recent developments in this rapidly growing field and, at the same time, provide an outlook on the future of iron-based photoredox catalysis.</p>}},
author = {{de Groot, Lisa H.M. and Ilic, Aleksandra and Schwarz, Jesper and Wärnmark, Kenneth}},
issn = {{0002-7863}},
language = {{eng}},
number = {{17}},
pages = {{9369--9388}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Journal of the American Chemical Society}},
title = {{Iron Photoredox Catalysis-Past, Present, and Future}},
url = {{http://dx.doi.org/10.1021/jacs.3c01000}},
doi = {{10.1021/jacs.3c01000}},
volume = {{145}},
year = {{2023}},
}