Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster
(2011) In Solid State Sciences 13(4). p.768-772- Abstract
- Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1987068
- author
- Jalilian, Ehsan and Lidin, Sven LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Copper(I) iodide cluster, Structure
- in
- Solid State Sciences
- volume
- 13
- issue
- 4
- pages
- 768 - 772
- publisher
- Elsevier
- external identifiers
-
- wos:000289965900014
- scopus:79953057620
- ISSN
- 1873-3085
- DOI
- 10.1016/j.solidstatesciences.2010.03.019
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- a8f4e0a2-a713-48c3-b2f9-3c968eda43d2 (old id 1987068)
- date added to LUP
- 2016-04-01 10:07:17
- date last changed
- 2022-01-25 19:57:16
@article{a8f4e0a2-a713-48c3-b2f9-3c968eda43d2, abstract = {{Two new compounds, [(C4H9)(4)P](2)[Cu5I7], and [(C4H9)(4) P](2)[Cu5I7]center dot CH3COCH2OH were synthesized by solvolysis and their crystal structures were solved. The first compound is disordered, but the solvate represents the first example of a fully ordered [Cu5I7](2-) cluster. It displays a molecular symmetry very close to C-2. Both compounds crystallize in space group P2(1)/c. (C) 2010 Elsevier Masson SAS. All rights reserved.}}, author = {{Jalilian, Ehsan and Lidin, Sven}}, issn = {{1873-3085}}, keywords = {{Copper(I) iodide cluster; Structure}}, language = {{eng}}, number = {{4}}, pages = {{768--772}}, publisher = {{Elsevier}}, series = {{Solid State Sciences}}, title = {{Bis(mu(3)-iodo)-pentakis(mu(2)-iodo)-penta-copper(I) - A fully ordered, isolated [Cu5I7](2-) cluster}}, url = {{http://dx.doi.org/10.1016/j.solidstatesciences.2010.03.019}}, doi = {{10.1016/j.solidstatesciences.2010.03.019}}, volume = {{13}}, year = {{2011}}, }