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Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)

Jalilian, Ehsan and Lidin, Sven LU (2010) In Journal of Solid State Chemistry 183(11). p.2656-2661
Abstract
Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide. (C) 2010 Elsevier Inc. All rights reserved.
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publishing date
type
Contribution to journal
publication status
published
subject
keywords
Structure, Copper(I), Iodide, Cluster
in
Journal of Solid State Chemistry
volume
183
issue
11
pages
2656 - 2661
publisher
Elsevier
external identifiers
  • wos:000284179800023
  • scopus:78049338110
ISSN
0022-4596
DOI
10.1016/j.jssc.2010.09.009
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
ad0080b2-bc81-4f82-b7cc-0f5f470c5bf8 (old id 1753161)
date added to LUP
2016-04-01 13:06:10
date last changed
2022-01-27 17:17:44
@article{ad0080b2-bc81-4f82-b7cc-0f5f470c5bf8,
  abstract     = {{Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group 141/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is non-bonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide. (C) 2010 Elsevier Inc. All rights reserved.}},
  author       = {{Jalilian, Ehsan and Lidin, Sven}},
  issn         = {{0022-4596}},
  keywords     = {{Structure; Copper(I); Iodide; Cluster}},
  language     = {{eng}},
  number       = {{11}},
  pages        = {{2656--2661}},
  publisher    = {{Elsevier}},
  series       = {{Journal of Solid State Chemistry}},
  title        = {{Dual graphs realized in the compounds di-mu(3)-4-mercaptopyridine catena-di-mu(2)-iodo-di-mu(3)-iodo-mu(4)-iodo penta copper(I) and di-mu(3)-4-mercaptopyridine-di-catena-iodo-di-mu(3)-iodo tri copper(I)}},
  url          = {{http://dx.doi.org/10.1016/j.jssc.2010.09.009}},
  doi          = {{10.1016/j.jssc.2010.09.009}},
  volume       = {{183}},
  year         = {{2010}},
}