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Shining light on the ferrous analogue : excited state dynamics of an Fe(ii) hexa-carbene scorpionate complex

Johnson, Catherine E. ; Deegbey, Mawuli ; Ilic, Aleksandra LU orcid ; Kaul, Nidhi ; Prakash, Om LU ; Wärnmark, Kenneth LU ; Jakubikova, Elena and Lomoth, Reiner (2025) In Dalton Transactions 54(9). p.3586-3590
Abstract

A ferrous complex bearing tris(carbene)borate ligands with imidazol-2-ylidene donors has been characterized by experimental and computational methods. Despite the pronounced destabilization of metal centered states by the exceptionally σ-donating ligand, the high-energy 3MLCT state of [Fe(ii)(phtmeimb)2] is rapidly deactivated by the barrierless conversion to the 3MC state.

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author
; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Dalton Transactions
volume
54
issue
9
pages
5 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:85217898676
  • pmid:39936935
ISSN
1477-9226
DOI
10.1039/d5dt00139k
language
English
LU publication?
yes
id
b6d0f271-b26a-43da-93e5-58634fd8d81a
date added to LUP
2025-06-25 08:44:28
date last changed
2025-11-12 22:25:10
@article{b6d0f271-b26a-43da-93e5-58634fd8d81a,
  abstract     = {{<p>A ferrous complex bearing tris(carbene)borate ligands with imidazol-2-ylidene donors has been characterized by experimental and computational methods. Despite the pronounced destabilization of metal centered states by the exceptionally σ-donating ligand, the high-energy <sup>3</sup>MLCT state of [Fe(ii)(phtmeimb)<sub>2</sub>] is rapidly deactivated by the barrierless conversion to the <sup>3</sup>MC state.</p>}},
  author       = {{Johnson, Catherine E. and Deegbey, Mawuli and Ilic, Aleksandra and Kaul, Nidhi and Prakash, Om and Wärnmark, Kenneth and Jakubikova, Elena and Lomoth, Reiner}},
  issn         = {{1477-9226}},
  language     = {{eng}},
  number       = {{9}},
  pages        = {{3586--3590}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Dalton Transactions}},
  title        = {{Shining light on the ferrous analogue : excited state dynamics of an Fe(ii) hexa-carbene scorpionate complex}},
  url          = {{http://dx.doi.org/10.1039/d5dt00139k}},
  doi          = {{10.1039/d5dt00139k}},
  volume       = {{54}},
  year         = {{2025}},
}