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Effects of Environment on Charge Recombination in Organo-Metal-Halide Perovskite Observed by Photoluminescence Microscopy and Spectroscopy

Li, Jun LU orcid (2021)
Abstract
Organo-metal-halide (OMH) perovskites form a new class of materials with
perovskite crystal structure ABX3 where A is an organic molecule, B is lead (Pb)
and X is a halide atom (I or Br). OMH perovskite semiconductors have been widely used in photovoltaics due to their very strong absorption of sun light, very suitable electrical properties, and the ease of preparation. Today the power conversion efficiency of record devices based on OMH is as large as 25.5%.
There are still many challenges for commercial application of OMH perovskite
based solar cells and other devices. One of the problems we can formulate as
sensitivity of the properties of OMP semiconductors and devices based on them on factors like electric field,... (More)
Organo-metal-halide (OMH) perovskites form a new class of materials with
perovskite crystal structure ABX3 where A is an organic molecule, B is lead (Pb)
and X is a halide atom (I or Br). OMH perovskite semiconductors have been widely used in photovoltaics due to their very strong absorption of sun light, very suitable electrical properties, and the ease of preparation. Today the power conversion efficiency of record devices based on OMH is as large as 25.5%.
There are still many challenges for commercial application of OMH perovskite
based solar cells and other devices. One of the problems we can formulate as
sensitivity of the properties of OMP semiconductors and devices based on them on factors like electric field, atmosphere, light, temperature and so on. Despite large efforts spent in the scientific community on investigation of the environmental effects on OMH perovskites and stability of devices many issues are still not wellunderstood.
In this thesis, I present results of several research projects where photoluminescence (PL) properties of OMH perovskites were studied by optical luminescence microscopy and spectroscopy under different environmental conditions such as humidity, electric field, local pressure and low temperature. We observed that water molecules can play an important role in the transformation of OMH perovskite from its intermediate phase containing solvent molecules to the perovskite crystal structure. We found that both electric field and local pressure and mechanical damage at nano-scale can create temporal PL quenching in OMH perovskites microand nanocrystals. We propose that PL quenching is induced by deep defects states created by electric field, pressure or mechanical manipulation. However, the destructive influence of all these factors on PL disappears several minutes after the influence was stopped due to self-healing properties of OHP. By comparing PL spectra and PL intensity and cryogenic temperatures and at room temperature we found that the concentration of shallow defect states and deep defect states are proportional to each other. (Less)
Please use this url to cite or link to this publication:
author
supervisor
opponent
  • Professor Hernán Ruy, Míguez García, Institute of Materials Science of Seville, Spanish Scientific Research Council
organization
publishing date
type
Thesis
publication status
published
subject
keywords
Environment, photoluminescence microscopy and spectroscopy, organo-metal-halide perovskite, charge recombination
edition
Media-Tryck
pages
169 pages
publisher
Lund University
defense location
Lecture Hall C, Kemicentrum, Naturvetarvägen 16, Lund. Join via zoom: https://lu-se.zoom.us/j/7020596553
defense date
2021-03-26 09:00:00
ISBN
978-91-7422-789-5
978-91-7422-788-8
language
English
LU publication?
yes
id
d76738c9-e551-4757-804f-21df95647b88
date added to LUP
2021-02-16 10:17:40
date last changed
2021-02-18 16:10:28
@phdthesis{d76738c9-e551-4757-804f-21df95647b88,
  abstract     = {{Organo-metal-halide (OMH) perovskites form a new class of materials with<br/>perovskite crystal structure ABX3 where A is an organic molecule, B is lead (Pb)<br/>and X is a halide atom (I or Br). OMH perovskite semiconductors have been widely used in photovoltaics due to their very strong absorption of sun light, very suitable electrical properties, and the ease of preparation. Today the power conversion efficiency of record devices based on OMH is as large as 25.5%.<br/>There are still many challenges for commercial application of OMH perovskite<br/>based solar cells and other devices. One of the problems we can formulate as<br/>sensitivity of the properties of OMP semiconductors and devices based on them on factors like electric field, atmosphere, light, temperature and so on. Despite large efforts spent in the scientific community on investigation of the environmental effects on OMH perovskites and stability of devices many issues are still not wellunderstood.<br/>In this thesis, I present results of several research projects where photoluminescence (PL) properties of OMH perovskites were studied by optical luminescence microscopy and spectroscopy under different environmental conditions such as humidity, electric field, local pressure and low temperature. We observed that water molecules can play an important role in the transformation of OMH perovskite from its intermediate phase containing solvent molecules to the perovskite crystal structure. We found that both electric field and local pressure and mechanical damage at nano-scale can create temporal PL quenching in OMH perovskites microand nanocrystals. We propose that PL quenching is induced by deep defects states created by electric field, pressure or mechanical manipulation. However, the destructive influence of all these factors on PL disappears several minutes after the influence was stopped due to self-healing properties of OHP. By comparing PL spectra and PL intensity and cryogenic temperatures and at room temperature we found that the concentration of shallow defect states and deep defect states are proportional to each other.}},
  author       = {{Li, Jun}},
  isbn         = {{978-91-7422-789-5}},
  keywords     = {{Environment; photoluminescence microscopy and spectroscopy; organo-metal-halide perovskite; charge recombination}},
  language     = {{eng}},
  month        = {{02}},
  publisher    = {{Lund University}},
  school       = {{Lund University}},
  title        = {{Effects of Environment on Charge Recombination in Organo-Metal-Halide Perovskite Observed by Photoluminescence Microscopy and Spectroscopy}},
  url          = {{https://lup.lub.lu.se/search/files/91453684/Jun_Li_web.pdf}},
  year         = {{2021}},
}