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A smectic dodecagonal quasicrystal

Metere, Alfredo ; Oleynikov, Peter ; Dzugutov, Mikhail and Lidin, Sven LU (2016) In Soft Matter 12(43). p.8869-8875
Abstract

We report a solid smectic phase that exhibits dodecagonal global order. It is composed of axially stacked hexagonally ordered particle layers, and its 12-fold rotational symmetry induced by the 30° rotation of adjacent layers with respect to each other. A quasicrystal was produced in a molecular-dynamics simulation of a single-component system of particles interacting via a spherically-symmetric potential. It was formed as a result of a first-order phase transition from an isotropic liquid state that occurred under constant-density cooling. This finding implies that a similarly structured quasicrystal can possibly be produced by the same class of systems as those forming smectic-B crystals. This quasicrystal can also be expected to... (More)

We report a solid smectic phase that exhibits dodecagonal global order. It is composed of axially stacked hexagonally ordered particle layers, and its 12-fold rotational symmetry induced by the 30° rotation of adjacent layers with respect to each other. A quasicrystal was produced in a molecular-dynamics simulation of a single-component system of particles interacting via a spherically-symmetric potential. It was formed as a result of a first-order phase transition from an isotropic liquid state that occurred under constant-density cooling. This finding implies that a similarly structured quasicrystal can possibly be produced by the same class of systems as those forming smectic-B crystals. This quasicrystal can also be expected to arise in a system of spherically-shaped colloidal particles with appropriately tuned potential.

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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Soft Matter
volume
12
issue
43
pages
7 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:84994639469
  • pmid:27722432
  • wos:000387988400008
ISSN
1744-683X
DOI
10.1039/c6sm01832g
language
English
LU publication?
yes
id
d90e0e95-6217-4398-9389-a6c5460ca1f1
date added to LUP
2017-02-21 14:57:28
date last changed
2024-03-31 01:30:10
@article{d90e0e95-6217-4398-9389-a6c5460ca1f1,
  abstract     = {{<p>We report a solid smectic phase that exhibits dodecagonal global order. It is composed of axially stacked hexagonally ordered particle layers, and its 12-fold rotational symmetry induced by the 30° rotation of adjacent layers with respect to each other. A quasicrystal was produced in a molecular-dynamics simulation of a single-component system of particles interacting via a spherically-symmetric potential. It was formed as a result of a first-order phase transition from an isotropic liquid state that occurred under constant-density cooling. This finding implies that a similarly structured quasicrystal can possibly be produced by the same class of systems as those forming smectic-B crystals. This quasicrystal can also be expected to arise in a system of spherically-shaped colloidal particles with appropriately tuned potential.</p>}},
  author       = {{Metere, Alfredo and Oleynikov, Peter and Dzugutov, Mikhail and Lidin, Sven}},
  issn         = {{1744-683X}},
  language     = {{eng}},
  number       = {{43}},
  pages        = {{8869--8875}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Soft Matter}},
  title        = {{A smectic dodecagonal quasicrystal}},
  url          = {{http://dx.doi.org/10.1039/c6sm01832g}},
  doi          = {{10.1039/c6sm01832g}},
  volume       = {{12}},
  year         = {{2016}},
}