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Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands

Kondrashov, Mikhail LU ; Gritcenko, Roman ; Fleckhaus, André LU and Wendt, Ola LU (2016) In Inorganica Chimica Acta 443. p.136-140
Abstract
The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.
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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Palladium, Bidentate ligands, Bridging ligands, C-H activation
in
Inorganica Chimica Acta
volume
443
pages
136 - 140
publisher
Elsevier
external identifiers
  • wos:000369070900019
  • scopus:84953911213
ISSN
0020-1693
DOI
10.1016/j.ica.2015.12.032
language
English
LU publication?
yes
id
dac125e1-d8cd-4d37-9f96-db728aad61e4 (old id 8728510)
date added to LUP
2016-04-01 12:57:22
date last changed
2025-10-14 13:03:14
@article{dac125e1-d8cd-4d37-9f96-db728aad61e4,
  abstract     = {{The cyclometallated dinuclear (2-phenyl-pyridine) palladium acetate and chloride [{PdCl(phpy)}(2)] and [{PdOAc(phpy)}(2)] were reacted with potentially bridging N- and S-donor ligands. The N,N-ligands bind with only one nitrogen and form monomeric products. The S,S-ligand binds in a chelate mode, also forming a monomeric complex. 3,3-Dimethyl glutarate, on the other hand, binds in a bridging mode. An X-ray structure of the complex with naphthyridine is presented. (C) 2016 Elsevier B.V. All rights reserved.}},
  author       = {{Kondrashov, Mikhail and Gritcenko, Roman and Fleckhaus, André and Wendt, Ola}},
  issn         = {{0020-1693}},
  keywords     = {{Palladium; Bidentate ligands; Bridging ligands; C-H activation}},
  language     = {{eng}},
  pages        = {{136--140}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Cyclometallated phenyl-pyridine palladium species. Monomeric complex formation with potentially bridging ligands}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2015.12.032}},
  doi          = {{10.1016/j.ica.2015.12.032}},
  volume       = {{443}},
  year         = {{2016}},
}