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Kinetics of the gas‐phase reactions of chlorine atoms with CH²F², CH³CCl³, and CF³CFH² over the temperature range 253–553 K

Nilsson, E. J. K. LU ; Johnson, M. S. ; Nielsen, O. J. ; Kaiser, E. W. and Wallington, T. J. (2009) In International Journal of Chemical Kinetics 41(6). p.401-406
Abstract
Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10−17 T2 exp(−1023/T) cm3 molecule−1 s−1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10−12 exp(−1630/T) cm3 molecule−1 s−1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10−12 exp(−2019/T) cm3 molecule−1 s−1 (253–313 K). Results are discussed with respect to the literature data.
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author
publishing date
type
Contribution to journal
publication status
published
subject
in
International Journal of Chemical Kinetics
volume
41
issue
6
pages
6 pages
publisher
John Wiley & Sons
ISSN
0538-8066
DOI
10.1002/kin.v41:6
language
English
LU publication?
no
id
f4ab59a4-883b-489b-b96b-968bc25e2921
alternative location
http://doi.wiley.com/10.1002/kin.20398
date added to LUP
2019-05-15 11:13:55
date last changed
2020-02-13 04:02:37
@article{f4ab59a4-883b-489b-b96b-968bc25e2921,
  abstract     = {Relative rate techniques were used to study the title reactions in 930–1200 mbar of N2 diluent. The reaction rate coefficients measured in the present work are summarized by the expressions k(Cl + CH2F2) = 1.19 × 10−17 T2 exp(−1023/T) cm3 molecule−1 s−1 (253–553 K), k(Cl + CH3CCl3) = 2.41 × 10−12 exp(−1630/T) cm3 molecule−1 s−1 (253–313 K), and k(Cl + CF3CFH2) = 1.27 × 10−12 exp(−2019/T) cm3 molecule−1 s−1 (253–313 K). Results are discussed with respect to the literature data.},
  author       = {Nilsson, E. J. K. and Johnson, M. S. and Nielsen, O. J. and Kaiser, E. W. and Wallington, T. J.},
  issn         = {0538-8066},
  language     = {eng},
  month        = {06},
  number       = {6},
  pages        = {401--406},
  publisher    = {John Wiley & Sons},
  series       = {International Journal of Chemical Kinetics},
  title        = {Kinetics of the gas‐phase reactions of chlorine atoms with CH²F², CH³CCl³, and CF³CFH² over the temperature range 253–553 K},
  url          = {http://dx.doi.org/10.1002/kin.v41:6},
  doi          = {10.1002/kin.v41:6},
  volume       = {41},
  year         = {2009},
}