A new compound in the Cu-In system - The synthesis and structure of Cu 10In7
(2008) In Zeitschrift fur Anorganische und Allgemeine Chemie 634(14). p.2589-2593- Abstract
A new binary phase, Cu10In7, was found during the investigation of the η?-phase field in the Cu-In system. Single crystals of Cu10In7 were grown from a melt under an inert atmosphere. The compound crystallizes in the monoclinic space group C2/m with cell parameters a = 13.8453(2)A ° , b = 11.8462(1)A ° , c = 6.7388(1)A ° and ?β = 91.063(1). The structure is based on a unit of face-sharing octahedra consisting of five Cu4In2 octahedra terminated by Cu5In octahedra at both ends. The crystal structure is closely related to the Cu11In9 structure type.
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- author
- Piao, Shuying and Lidin, Sven LU
- publishing date
- 2008-11-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Copper, Crystal structure, Indium, Phase diagram
- in
- Zeitschrift fur Anorganische und Allgemeine Chemie
- volume
- 634
- issue
- 14
- pages
- 5 pages
- publisher
- Wiley-Blackwell
- external identifiers
-
- scopus:55549123873
- ISSN
- 0044-2313
- DOI
- 10.1002/zaac.200800275
- language
- English
- LU publication?
- no
- id
- f9837910-7a84-43b3-bda1-9452b3cc51e2
- date added to LUP
- 2019-04-08 15:10:00
- date last changed
- 2022-01-31 18:46:45
@article{f9837910-7a84-43b3-bda1-9452b3cc51e2, abstract = {{<p>A new binary phase, Cu<sub>10</sub>In<sub>7</sub>, was found during the investigation of the η?-phase field in the Cu-In system. Single crystals of Cu<sub>10</sub>In<sub>7</sub> were grown from a melt under an inert atmosphere. The compound crystallizes in the monoclinic space group C2/m with cell parameters a = 13.8453(2)A ° , b = 11.8462(1)A ° , c = 6.7388(1)A ° and ?β = 91.063(1). The structure is based on a unit of face-sharing octahedra consisting of five Cu<sub>4</sub>In<sub>2</sub> octahedra terminated by Cu<sub>5</sub>In octahedra at both ends. The crystal structure is closely related to the Cu<sub>11</sub>In<sub>9</sub> structure type.</p>}}, author = {{Piao, Shuying and Lidin, Sven}}, issn = {{0044-2313}}, keywords = {{Copper; Crystal structure; Indium; Phase diagram}}, language = {{eng}}, month = {{11}}, number = {{14}}, pages = {{2589--2593}}, publisher = {{Wiley-Blackwell}}, series = {{Zeitschrift fur Anorganische und Allgemeine Chemie}}, title = {{A new compound in the Cu-In system - The synthesis and structure of Cu <sub>10</sub>In<sub>7</sub>}}, url = {{http://dx.doi.org/10.1002/zaac.200800275}}, doi = {{10.1002/zaac.200800275}}, volume = {{634}}, year = {{2008}}, }