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Electronic structure of nickel porphyrin NiP : Study by X-ray photoelectron and absorption spectroscopy

Svirskiy, Gleb I ; Sergeeva, N. N. ; Krasnikov, S A ; Vinogradov, N. A. LU orcid ; Sergeeva, Yu N. ; Cafolla, A. A. ; Preobrajenski, A. B. LU and Vinogradov, A S (2017) In Physics of the Solid State 59(2). p.368-377
Abstract

Energy distributions and properties of the occupied and empty electronic states for a planar complex of nickel porphyrin NiP are studied by X-ray photoemission and absorption spectroscopy techniques. As a result of the analysis of the experimental spectra of valence photoemission, the nature and energy positions of the highest occupied electronic states were determined: the highest occupied state is formed mostly by atomic states of the porphine ligand; the following two states are associated with 3d states of the nickel atom. It was found that the lowest empty state is specific and is described by the σ-type b1g MO formed by empty Ni3dx2−y2-states and occupied 2p-states of lone electron pairs of nitrogen atoms. This specific... (More)

Energy distributions and properties of the occupied and empty electronic states for a planar complex of nickel porphyrin NiP are studied by X-ray photoemission and absorption spectroscopy techniques. As a result of the analysis of the experimental spectra of valence photoemission, the nature and energy positions of the highest occupied electronic states were determined: the highest occupied state is formed mostly by atomic states of the porphine ligand; the following two states are associated with 3d states of the nickel atom. It was found that the lowest empty state is specific and is described by the σ-type b1g MO formed by empty Ni3dx2−y2-states and occupied 2p-states of lone electron pairs of nitrogen atoms. This specific nature of the lowest empty state is a consequence of the donor–acceptor chemical bond in NiP.

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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physics of the Solid State
volume
59
issue
2
pages
10 pages
publisher
MAIK Nauka/Interperiodica
external identifiers
  • scopus:85013498162
  • wos:000394986300028
ISSN
1063-7834
DOI
10.1134/S1063783417020299
language
English
LU publication?
yes
id
fb4623ca-0b0e-4485-94ab-4c7feeed55fb
date added to LUP
2017-03-08 11:56:22
date last changed
2025-01-07 09:17:52
@article{fb4623ca-0b0e-4485-94ab-4c7feeed55fb,
  abstract     = {{<p>Energy distributions and properties of the occupied and empty electronic states for a planar complex of nickel porphyrin NiP are studied by X-ray photoemission and absorption spectroscopy techniques. As a result of the analysis of the experimental spectra of valence photoemission, the nature and energy positions of the highest occupied electronic states were determined: the highest occupied state is formed mostly by atomic states of the porphine ligand; the following two states are associated with 3d states of the nickel atom. It was found that the lowest empty state is specific and is described by the σ-type b<sub>1g</sub> MO formed by empty Ni3dx2−y2-states and occupied 2p-states of lone electron pairs of nitrogen atoms. This specific nature of the lowest empty state is a consequence of the donor–acceptor chemical bond in NiP.</p>}},
  author       = {{Svirskiy, Gleb I and Sergeeva, N. N. and Krasnikov, S A and Vinogradov, N. A. and Sergeeva, Yu N. and Cafolla, A. A. and Preobrajenski, A. B. and Vinogradov, A S}},
  issn         = {{1063-7834}},
  language     = {{eng}},
  month        = {{02}},
  number       = {{2}},
  pages        = {{368--377}},
  publisher    = {{MAIK Nauka/Interperiodica}},
  series       = {{Physics of the Solid State}},
  title        = {{Electronic structure of nickel porphyrin NiP : Study by X-ray photoelectron and absorption spectroscopy}},
  url          = {{http://dx.doi.org/10.1134/S1063783417020299}},
  doi          = {{10.1134/S1063783417020299}},
  volume       = {{59}},
  year         = {{2017}},
}