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Acetate formation during the ethanol oxidation on Rh(1 1 1)

Resta, Andrea LU ; Blomquist, Jakob LU ; Gustafson, Johan LU ; Karhu, H. ; Mikkelsen, Anders LU ; Lundgren, Edvin LU ; Uvdal, Per LU and Andersen, Jesper N LU (2006) In Surface Science 600(24). p.5136-5141
Abstract
The catalytic cracking of ethanol on clean and oxygen precovered Rh(1 1 1) surfaces has been studied by a combination of synchrotron based high-resolution core level spectroscopy and surface infrared spectroscopy. On the clean surface the decomposition of ethanol occurs without any formation of atomic oxygen. The presence of oxygen on the surface changes the reactivity significantly and previous termacetatenext term (CH3COO) was identified as an important surface intermediate in the ethanol oxidation.
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author
; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Surface Science
volume
600
issue
24
pages
5136 - 5141
publisher
Elsevier
external identifiers
  • wos:000243248100008
  • scopus:33845200534
ISSN
0039-6028
DOI
10.1016/j.susc.2006.08.039
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Synchrotron Radiation Research (011013009), Inorganic chemistry (ceased) (LUR000010), Chemical Physics (S) (011001060)
id
fefd10f4-e5a6-41ca-8aed-608f94f35bf1 (old id 634074)
date added to LUP
2016-04-01 15:35:10
date last changed
2022-01-28 06:05:36
@article{fefd10f4-e5a6-41ca-8aed-608f94f35bf1,
  abstract     = {{The catalytic cracking of ethanol on clean and oxygen precovered Rh(1 1 1) surfaces has been studied by a combination of synchrotron based high-resolution core level spectroscopy and surface infrared spectroscopy. On the clean surface the decomposition of ethanol occurs without any formation of atomic oxygen. The presence of oxygen on the surface changes the reactivity significantly and previous termacetatenext term (CH3COO) was identified as an important surface intermediate in the ethanol oxidation.}},
  author       = {{Resta, Andrea and Blomquist, Jakob and Gustafson, Johan and Karhu, H. and Mikkelsen, Anders and Lundgren, Edvin and Uvdal, Per and Andersen, Jesper N}},
  issn         = {{0039-6028}},
  language     = {{eng}},
  number       = {{24}},
  pages        = {{5136--5141}},
  publisher    = {{Elsevier}},
  series       = {{Surface Science}},
  title        = {{Acetate formation during the ethanol oxidation on Rh(1 1 1)}},
  url          = {{http://dx.doi.org/10.1016/j.susc.2006.08.039}},
  doi          = {{10.1016/j.susc.2006.08.039}},
  volume       = {{600}},
  year         = {{2006}},
}