Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K
(2010) In Chemical Physics Letters 494(4-6). p.160-162- Abstract
The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1.
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- author
- Nilsson, Elna J K LU ; Hoff, Janus ; Nielsen, Ole John and Johnson, Matthew S.
- organization
- publishing date
- 2010-07-19
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics Letters
- volume
- 494
- issue
- 4-6
- pages
- 3 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:77955309603
- ISSN
- 0009-2614
- DOI
- 10.1016/j.cplett.2010.06.026
- language
- English
- LU publication?
- yes
- id
- bcdb277e-719a-4b37-ad0a-12073d8be0d3
- date added to LUP
- 2016-10-04 10:33:13
- date last changed
- 2022-01-30 06:34:56
@article{bcdb277e-719a-4b37-ad0a-12073d8be0d3, abstract = {{<p>The reaction CHCl<sub>3</sub> + Cl → CCl<sub>3</sub> + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N<sub>2</sub> diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10<sup>-12</sup> exp((-1011 ± 24)/T) cm<sup>3</sup> molecule<sup>-1</sup> s<sup>-1</sup>.</p>}}, author = {{Nilsson, Elna J K and Hoff, Janus and Nielsen, Ole John and Johnson, Matthew S.}}, issn = {{0009-2614}}, language = {{eng}}, month = {{07}}, number = {{4-6}}, pages = {{160--162}}, publisher = {{Elsevier}}, series = {{Chemical Physics Letters}}, title = {{Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K}}, url = {{http://dx.doi.org/10.1016/j.cplett.2010.06.026}}, doi = {{10.1016/j.cplett.2010.06.026}}, volume = {{494}}, year = {{2010}}, }