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Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K

Nilsson, Elna J K LU orcid ; Hoff, Janus ; Nielsen, Ole John and Johnson, Matthew S. (2010) In Chemical Physics Letters 494(4-6). p.160-162
Abstract

The reaction CHCl3 + Cl → CCl3 + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N2 diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10-12 exp((-1011 ± 24)/T) cm3 molecule-1 s-1.

Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Chemical Physics Letters
volume
494
issue
4-6
pages
3 pages
publisher
Elsevier
external identifiers
  • scopus:77955309603
ISSN
0009-2614
DOI
10.1016/j.cplett.2010.06.026
language
English
LU publication?
yes
id
bcdb277e-719a-4b37-ad0a-12073d8be0d3
date added to LUP
2016-10-04 10:33:13
date last changed
2022-01-30 06:34:56
@article{bcdb277e-719a-4b37-ad0a-12073d8be0d3,
  abstract     = {{<p>The reaction CHCl<sub>3</sub> + Cl → CCl<sub>3</sub> + HCl was studied in the atmospherically relevant temperature range from 253 to 313 K and in 930 mbar of N<sub>2</sub> diluent using the relative rate method. A temperature dependent reaction rate constant, valid in the temperature range 220-330 K, was determined by a fit to the result of the present study and that of Orlando (1999); k = (3.77 ± 0.32) × 10<sup>-12</sup> exp((-1011 ± 24)/T) cm<sup>3</sup> molecule<sup>-1</sup> s<sup>-1</sup>.</p>}},
  author       = {{Nilsson, Elna J K and Hoff, Janus and Nielsen, Ole John and Johnson, Matthew S.}},
  issn         = {{0009-2614}},
  language     = {{eng}},
  month        = {{07}},
  number       = {{4-6}},
  pages        = {{160--162}},
  publisher    = {{Elsevier}},
  series       = {{Chemical Physics Letters}},
  title        = {{Kinetics of the reaction of Cl atoms with CHCl3 over the temperature range 253-313 K}},
  url          = {{http://dx.doi.org/10.1016/j.cplett.2010.06.026}},
  doi          = {{10.1016/j.cplett.2010.06.026}},
  volume       = {{494}},
  year         = {{2010}},
}