Wall-collision line broadening of molecular oxygen within nanoporous materials
(2011) In Physical Review A (Atomic, Molecular and Optical Physics) 84(4).- Abstract
- Wall-collision broadening of near-infrared absorption lines of molecular oxygen confined in nanoporous zirconia is studied by employing high-resolution diode-laser spectroscopy. The broadening is studied for pores of different sizes under a range of pressures, providing new insights on how wall collisions and intermolecular collisions influence the total spectroscopic line profile. The pressure series show that wall-collision broadening is relatively more prominent under reduced pressures, enabling sensitive means to probe pore sizes of porous materials. In addition, we show that the total wall-collision-broadened profile strongly deviates from a Voigt profile and that wall-collision broadening exhibits an additive-like behavior to the... (More)
- Wall-collision broadening of near-infrared absorption lines of molecular oxygen confined in nanoporous zirconia is studied by employing high-resolution diode-laser spectroscopy. The broadening is studied for pores of different sizes under a range of pressures, providing new insights on how wall collisions and intermolecular collisions influence the total spectroscopic line profile. The pressure series show that wall-collision broadening is relatively more prominent under reduced pressures, enabling sensitive means to probe pore sizes of porous materials. In addition, we show that the total wall-collision-broadened profile strongly deviates from a Voigt profile and that wall-collision broadening exhibits an additive-like behavior to the pressure and Doppler broadening. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2211661
- author
- Xu, Can LU ; Lewander, Märta LU ; Andersson-Engels, Stefan LU ; Adolfsson, Erik ; Svensson, Tomas LU and Svanberg, Sune LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review A (Atomic, Molecular and Optical Physics)
- volume
- 84
- issue
- 4
- publisher
- American Physical Society
- external identifiers
-
- wos:000295712700012
- scopus:80053998583
- ISSN
- 1050-2947
- DOI
- 10.1103/PhysRevA.84.042705
- language
- English
- LU publication?
- yes
- id
- e08a5f14-5e14-4e39-a548-3e810168136d (old id 2211661)
- date added to LUP
- 2016-04-01 11:08:56
- date last changed
- 2022-04-05 00:33:14
@article{e08a5f14-5e14-4e39-a548-3e810168136d,
abstract = {{Wall-collision broadening of near-infrared absorption lines of molecular oxygen confined in nanoporous zirconia is studied by employing high-resolution diode-laser spectroscopy. The broadening is studied for pores of different sizes under a range of pressures, providing new insights on how wall collisions and intermolecular collisions influence the total spectroscopic line profile. The pressure series show that wall-collision broadening is relatively more prominent under reduced pressures, enabling sensitive means to probe pore sizes of porous materials. In addition, we show that the total wall-collision-broadened profile strongly deviates from a Voigt profile and that wall-collision broadening exhibits an additive-like behavior to the pressure and Doppler broadening.}},
author = {{Xu, Can and Lewander, Märta and Andersson-Engels, Stefan and Adolfsson, Erik and Svensson, Tomas and Svanberg, Sune}},
issn = {{1050-2947}},
language = {{eng}},
number = {{4}},
publisher = {{American Physical Society}},
series = {{Physical Review A (Atomic, Molecular and Optical Physics)}},
title = {{Wall-collision line broadening of molecular oxygen within nanoporous materials}},
url = {{https://lup.lub.lu.se/search/files/2417197/2426264.pdf}},
doi = {{10.1103/PhysRevA.84.042705}},
volume = {{84}},
year = {{2011}},
}