Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.
(2012) In Carbohydrate Research 353(Online 24 March 2012). p.92-95- Abstract
- The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2519040
- author
- Johnsson, Richard LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Carbohydrate Research
- volume
- 353
- issue
- Online 24 March 2012
- pages
- 92 - 95
- publisher
- Elsevier
- external identifiers
-
- wos:000304053900012
- pmid:22533917
- scopus:84861096808
- pmid:22533917
- ISSN
- 1873-426X
- DOI
- 10.1016/j.carres.2012.03.016
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- be34b210-aeb0-4f39-9047-68a81a33d067 (old id 2519040)
- date added to LUP
- 2016-04-01 10:32:21
- date last changed
- 2022-02-17 19:03:31
@article{be34b210-aeb0-4f39-9047-68a81a33d067, abstract = {{The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.}}, author = {{Johnsson, Richard}}, issn = {{1873-426X}}, language = {{eng}}, number = {{Online 24 March 2012}}, pages = {{92--95}}, publisher = {{Elsevier}}, series = {{Carbohydrate Research}}, title = {{Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.}}, url = {{https://lup.lub.lu.se/search/files/1930479/2539511.pdf}}, doi = {{10.1016/j.carres.2012.03.016}}, volume = {{353}}, year = {{2012}}, }