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Novel materials for Cr(VI)adsorption by magnetic titanium nanotubes coated phosphorene

Lin, Yu Jung ; Chen, Jia Jia ; Cao, Wen Zhi ; Persson, Kenneth M. LU ; Ouyang, Tong ; Zhang, Linus LU orcid ; Xie, Xiaodan ; Liu, Fang ; Li, Jing LU and Chang, Chang Tang (2019) In Journal of Molecular Liquids 287.
Abstract


The accumulation of Cr(VI)will cause mutagenic and carcinogenic effects on humans. Therefore, the standard regulations have been governed by the EPA to control the chromium content in the effluent and drinking water and have made it mandatory [1]. For the better recovery of the adsorbent; Magnetic nano particle based phosphorene titanium nano tubes were used for the first time in action which has been proven to be superior for the Chormium pollutants. MNP-PN-TNT (Magnetic nanoparticle-Phosphorene-Titanium nano tubes)was synthesized from hydrothermal method in this study. The prepared material is used for effective removal of Cr(VI)from the water by adsorption technique in... (More)


The accumulation of Cr(VI)will cause mutagenic and carcinogenic effects on humans. Therefore, the standard regulations have been governed by the EPA to control the chromium content in the effluent and drinking water and have made it mandatory [1]. For the better recovery of the adsorbent; Magnetic nano particle based phosphorene titanium nano tubes were used for the first time in action which has been proven to be superior for the Chormium pollutants. MNP-PN-TNT (Magnetic nanoparticle-Phosphorene-Titanium nano tubes)was synthesized from hydrothermal method in this study. The prepared material is used for effective removal of Cr(VI)from the water by adsorption technique in acidic environment. The adsorption capacity was found to be 35 mg g
−1
at the initial concentration of 50 mg L
−1
maintainingthe temperature under 45 °C. The optimal operation condition is under pH 9, temperature of 25 °C, and dosage of 0.8 g L
−1
obtained from RSM (Response Surface Methdology). The adsorption process of MNP-PN-TNT is conformed with a pseudo-second-order kinetic model. Cr(VI)adsorption behavior with MNP-PN-TNT, is spontaneous from the results of thermodynamics analysis. The adsorption mechanism of Cr(VI)with MNP-PN-TNT was evident by O1s, C1s, Cr 2p, Ti 2p, Fe 2p and P 2p of XPS. Cr(VI)is adsorbed with MNP-PN-TNT, in randomness during the adsorption process.

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author
; ; ; ; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Adsorption, Hexavalent chromium, MNP-PN-TNT, Response Surface Methdology
in
Journal of Molecular Liquids
volume
287
article number
110826
publisher
Elsevier
external identifiers
  • scopus:85065825497
ISSN
0167-7322
DOI
10.1016/j.molliq.2019.04.103
language
English
LU publication?
yes
id
0383b8a5-f4c9-4e21-a0b8-2b95f4eb5148
date added to LUP
2019-05-28 08:23:21
date last changed
2022-04-26 00:31:48
@article{0383b8a5-f4c9-4e21-a0b8-2b95f4eb5148,
  abstract     = {{<p><br>
                                                         The accumulation of Cr(VI)will cause mutagenic and carcinogenic effects on humans. Therefore, the standard regulations have been governed by the EPA to control the chromium content in the effluent and drinking water and have made it mandatory [1]. For the better recovery of the adsorbent; Magnetic nano particle based phosphorene titanium nano tubes were used for the first time in action which has been proven to be superior for the Chormium pollutants. MNP-PN-TNT (Magnetic nanoparticle-Phosphorene-Titanium nano tubes)was synthesized from hydrothermal method in this study. The prepared material is used for effective removal of Cr(VI)from the water by adsorption technique in acidic environment. The adsorption capacity was found to be 35 mg g                             <br>
                            <sup>−1</sup><br>
                                                          at the initial concentration of 50 mg L                             <br>
                            <sup>−1</sup><br>
                                                         maintainingthe temperature under 45 °C. The optimal operation condition is under pH 9, temperature of 25 °C, and dosage of 0.8 g L                             <br>
                            <sup>−1</sup><br>
                                                          obtained from RSM (Response Surface Methdology). The adsorption process of MNP-PN-TNT is conformed with a pseudo-second-order kinetic model. Cr(VI)adsorption behavior with MNP-PN-TNT, is spontaneous from the results of thermodynamics analysis. The adsorption mechanism of Cr(VI)with MNP-PN-TNT was evident by O1s, C1s, Cr 2p, Ti 2p, Fe 2p and P 2p of XPS. Cr(VI)is adsorbed with MNP-PN-TNT, in randomness during the adsorption process.                         <br>
                        </p>}},
  author       = {{Lin, Yu Jung and Chen, Jia Jia and Cao, Wen Zhi and Persson, Kenneth M. and Ouyang, Tong and Zhang, Linus and Xie, Xiaodan and Liu, Fang and Li, Jing and Chang, Chang Tang}},
  issn         = {{0167-7322}},
  keywords     = {{Adsorption; Hexavalent chromium; MNP-PN-TNT; Response Surface Methdology}},
  language     = {{eng}},
  publisher    = {{Elsevier}},
  series       = {{Journal of Molecular Liquids}},
  title        = {{Novel materials for Cr(VI)adsorption by magnetic titanium nanotubes coated phosphorene}},
  url          = {{http://dx.doi.org/10.1016/j.molliq.2019.04.103}},
  doi          = {{10.1016/j.molliq.2019.04.103}},
  volume       = {{287}},
  year         = {{2019}},
}