Dynamic phase diagram and onion formation in the system C10E3/D2O
(2003) In Colloids and Surfaces A: Physicochemical and Engineering Aspects 228(1-3). p.85-90- Abstract
- The influence of the shear on the lamellar phase, L, of the system C10E3/D2O was studied along an isoplethal path (40 wt.% C10E3) in the temperature range 25-42degreesC. A dynamic phase diagram was determined by steady-state rheometry, where by shear action the lamellar phase was transformed into multilamellar vesicles (MLVs) ("onions"). The location of "onions" in the dynamic phase diagram, depends only on the temperature and the applied shear rate, and not on the shear history. The classical lamellar phase structure is stable at rest and at low shear rates. When exposed to higher shear rates, the lamellar structure is transformed into onions. The transition from lamellae to onions is shifted to higher shear rates with increasing... (More)
- The influence of the shear on the lamellar phase, L, of the system C10E3/D2O was studied along an isoplethal path (40 wt.% C10E3) in the temperature range 25-42degreesC. A dynamic phase diagram was determined by steady-state rheometry, where by shear action the lamellar phase was transformed into multilamellar vesicles (MLVs) ("onions"). The location of "onions" in the dynamic phase diagram, depends only on the temperature and the applied shear rate, and not on the shear history. The classical lamellar phase structure is stable at rest and at low shear rates. When exposed to higher shear rates, the lamellar structure is transformed into onions. The transition from lamellae to onions is shifted to higher shear rates with increasing temperature. In a range of shear rates in between the stable lamellae and
stable onion structure, the transition is incomplete. The transformation of lamellae into onions appears to be governed by the imposed strain, in agreement with earlier studies. The effect of temperature can be understood from the general property of nonionic surfactants where the monolayer spontaneous curvature decreases with increasing temperature. (C) 2003 Published by Elsevier B.V. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/122128
- author
- Oliviero, C ; Coppola, L ; Gianferri, R ; Nicotera, I and Olsson, Ulf LU
- organization
- publishing date
- 2003
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Lamellar phase, Multilamellar vesicles, Onions, Tri-ethyleneglycol mono n-decyl ether (C10E3), Steady state rheometry, Dynamic-phase-diagram
- in
- Colloids and Surfaces A: Physicochemical and Engineering Aspects
- volume
- 228
- issue
- 1-3
- pages
- 85 - 90
- publisher
- Elsevier
- external identifiers
-
- wos:000187181300010
- scopus:0242509294
- ISSN
- 0927-7757
- DOI
- 10.1016/S0927-7757(03)00356-X
- language
- English
- LU publication?
- yes
- id
- 5567a035-dc3b-4ae9-8ee2-33d004424bf0 (old id 122128)
- date added to LUP
- 2016-04-01 16:30:34
- date last changed
- 2022-01-28 20:12:20
@article{5567a035-dc3b-4ae9-8ee2-33d004424bf0,
abstract = {{The influence of the shear on the lamellar phase, L, of the system C10E3/D2O was studied along an isoplethal path (40 wt.% C10E3) in the temperature range 25-42degreesC. A dynamic phase diagram was determined by steady-state rheometry, where by shear action the lamellar phase was transformed into multilamellar vesicles (MLVs) ("onions"). The location of "onions" in the dynamic phase diagram, depends only on the temperature and the applied shear rate, and not on the shear history. The classical lamellar phase structure is stable at rest and at low shear rates. When exposed to higher shear rates, the lamellar structure is transformed into onions. The transition from lamellae to onions is shifted to higher shear rates with increasing temperature. In a range of shear rates in between the stable lamellae and<br/><br>
stable onion structure, the transition is incomplete. The transformation of lamellae into onions appears to be governed by the imposed strain, in agreement with earlier studies. The effect of temperature can be understood from the general property of nonionic surfactants where the monolayer spontaneous curvature decreases with increasing temperature. (C) 2003 Published by Elsevier B.V.}},
author = {{Oliviero, C and Coppola, L and Gianferri, R and Nicotera, I and Olsson, Ulf}},
issn = {{0927-7757}},
keywords = {{Lamellar phase; Multilamellar vesicles; Onions; Tri-ethyleneglycol mono n-decyl ether (C10E3); Steady state rheometry; Dynamic-phase-diagram}},
language = {{eng}},
number = {{1-3}},
pages = {{85--90}},
publisher = {{Elsevier}},
series = {{Colloids and Surfaces A: Physicochemical and Engineering Aspects}},
title = {{Dynamic phase diagram and onion formation in the system C10E3/D2O}},
url = {{http://dx.doi.org/10.1016/S0927-7757(03)00356-X}},
doi = {{10.1016/S0927-7757(03)00356-X}},
volume = {{228}},
year = {{2003}},
}