Modeling of Bottle-Brush Polymer Adsorption onto Mica and Silica Surfaces: Effect of Side-Chain Length
(2010) In Macromolecules 43(4). p.2076-2083- Abstract
- Adsorption of a series of charged bottle-brush polymers with side chains of different length on solid surfaces is modeled using a lattice mean-field theory. The bottle-brush polymers are modeled Lis being composed of two types of main-chain segments: charged segments and uncharged segments with ill attached side chain. The composition variable X denotes the percentage of charged main-chain segments and ranges from X = 0 (uncharged bottle-brush polymer) to X = 100 (linear polyelectrolyte). Two types of surfaces are considered: mica-like and silica-like. The mica-like surface possesses a constant negative surface charge density and no nonelectrostatic affinity for either main-chain or side-chain segments, whereas the silica-like Surface has... (More)
- Adsorption of a series of charged bottle-brush polymers with side chains of different length on solid surfaces is modeled using a lattice mean-field theory. The bottle-brush polymers are modeled Lis being composed of two types of main-chain segments: charged segments and uncharged segments with ill attached side chain. The composition variable X denotes the percentage of charged main-chain segments and ranges from X = 0 (uncharged bottle-brush polymer) to X = 100 (linear polyelectrolyte). Two types of surfaces are considered: mica-like and silica-like. The mica-like surface possesses a constant negative surface charge density and no nonelectrostatic affinity for either main-chain or side-chain segments, whereas the silica-like Surface has a constant negative surface potential and a positive affinity for the side chains of the bottle-brush polymers. With the mica-like Surface. ill low X the surface excess becomes smaller and at X >= 25 it becomes larger with increasing side-chain length. Hence, the value of X at which the surface excess displays a maximum increases with the side-chain length. However, with the silica-like Surface the surface excess increases with increasing side-chain length at all X < 100, and the maximum of the surface excess appears at X approximate to 10 independent of the side-chain length. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1568850
- author
- Linse, Per LU and Claesson, Per M.
- organization
- publishing date
- 2010
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Macromolecules
- volume
- 43
- issue
- 4
- pages
- 2076 - 2083
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000274529800053
- scopus:77249141497
- ISSN
- 0024-9297
- DOI
- 10.1021/ma902577m
- language
- English
- LU publication?
- yes
- id
- 133ecb03-9b80-4ea3-955c-c8675d526e36 (old id 1568850)
- date added to LUP
- 2016-04-01 09:56:29
- date last changed
- 2022-01-25 18:09:45
@article{133ecb03-9b80-4ea3-955c-c8675d526e36,
abstract = {{Adsorption of a series of charged bottle-brush polymers with side chains of different length on solid surfaces is modeled using a lattice mean-field theory. The bottle-brush polymers are modeled Lis being composed of two types of main-chain segments: charged segments and uncharged segments with ill attached side chain. The composition variable X denotes the percentage of charged main-chain segments and ranges from X = 0 (uncharged bottle-brush polymer) to X = 100 (linear polyelectrolyte). Two types of surfaces are considered: mica-like and silica-like. The mica-like surface possesses a constant negative surface charge density and no nonelectrostatic affinity for either main-chain or side-chain segments, whereas the silica-like Surface has a constant negative surface potential and a positive affinity for the side chains of the bottle-brush polymers. With the mica-like Surface. ill low X the surface excess becomes smaller and at X >= 25 it becomes larger with increasing side-chain length. Hence, the value of X at which the surface excess displays a maximum increases with the side-chain length. However, with the silica-like Surface the surface excess increases with increasing side-chain length at all X < 100, and the maximum of the surface excess appears at X approximate to 10 independent of the side-chain length.}},
author = {{Linse, Per and Claesson, Per M.}},
issn = {{0024-9297}},
language = {{eng}},
number = {{4}},
pages = {{2076--2083}},
publisher = {{The American Chemical Society (ACS)}},
series = {{Macromolecules}},
title = {{Modeling of Bottle-Brush Polymer Adsorption onto Mica and Silica Surfaces: Effect of Side-Chain Length}},
url = {{http://dx.doi.org/10.1021/ma902577m}},
doi = {{10.1021/ma902577m}},
volume = {{43}},
year = {{2010}},
}