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Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]

Jalilian, Ehsan and Lidin, Sven LU (2010) In Acta Crystallographica. Section C: Crystal Structure Communications 66. p.227-230
Abstract
The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the... (More)
The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis. (Less)
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
66
pages
227 - 230
publisher
International Union of Crystallography
external identifiers
  • wos:000280708100009
  • scopus:77955464014
  • pmid:20679711
ISSN
0108-2701
DOI
10.1107/S0108270110027149
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
id
7eaeb347-2c53-4b53-948e-c6510ef086b5 (old id 1677239)
date added to LUP
2016-04-01 14:44:03
date last changed
2022-04-06 20:13:14
@article{7eaeb347-2c53-4b53-948e-c6510ef086b5,
  abstract     = {{The title compound, {(C14H16P)[Cu5I6]} (n) , prepared from the reaction between copper powder, iodine and dimethyldiphenylphosphonium iodide in hydroxyacetone, features an anion that consists of a continuous two-dimensional Cu-I sheet [Cu-I = 2.5960 (14)-2.6994 (13) A and Cu-I-Cu = 63.28 (5)-114.25 (5)degrees]. The cation, which lies on a mirror plane, is a typical dimethyldiphenylphosphonium ion. The structure shows a strong tendency towards segregation of the inorganic and organic parts of the structure into separate subspaces. The two-dimensional Cu-I sheet displays a pronounced subcell with pseudo-tetragonal symmetry that is broken by ordered vacancies on the Cu position. The symmetry is further reduced by the orientation of the interleaved organic counter-ion that is inclined with respect to the pseudo-mirror planes defined by the Cu-I sheet normal, perpendicular to the b axis.}},
  author       = {{Jalilian, Ehsan and Lidin, Sven}},
  issn         = {{0108-2701}},
  language     = {{eng}},
  pages        = {{227--230}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica. Section C: Crystal Structure Communications}},
  title        = {{Poly[dimethyldiphenylphosphonium [di-mu(4)-iodido-tetra-mu(3)-iodido-pentacopper(I)]]}},
  url          = {{http://dx.doi.org/10.1107/S0108270110027149}},
  doi          = {{10.1107/S0108270110027149}},
  volume       = {{66}},
  year         = {{2010}},
}