Two for the price of one - Resolvable polymorphism in a 'single crystal' of α- and β-Sb3O4I
(2009) In Solid State Sciences 11(1). p.24-28- Abstract
The title compound forms as biphasic single crystals containing the α- and β-polymorphs. The structure of both polymorphs was solved and refined from single crystal X-ray data in a simultaneous refinement. The structures consist of rods of composition Sb3O4 separated by isolated iodine ions. The two phases differ only in the next nearest neighbour arrangement. The orthorhombic α-phase crystallizes in space group Pbn21, and the monoclinic β-phase in space group P21/n.
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https://lup.lub.lu.se/record/1d50ce9f-5c1f-464f-82a5-ba979f63ea45
- author
- Hugonin, Zuzana ; Johnsson, Mats LU and Lidin, Sven LU
- publishing date
- 2009-01-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Multiphase crystal, Oxo-halide, Stereochemically active lone pair
- in
- Solid State Sciences
- volume
- 11
- issue
- 1
- pages
- 5 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:57849092124
- ISSN
- 1293-2558
- DOI
- 10.1016/j.solidstatesciences.2008.04.028
- language
- English
- LU publication?
- no
- id
- 1d50ce9f-5c1f-464f-82a5-ba979f63ea45
- date added to LUP
- 2019-04-08 15:08:13
- date last changed
- 2022-04-02 07:46:15
@article{1d50ce9f-5c1f-464f-82a5-ba979f63ea45, abstract = {{<p>The title compound forms as biphasic single crystals containing the α- and β-polymorphs. The structure of both polymorphs was solved and refined from single crystal X-ray data in a simultaneous refinement. The structures consist of rods of composition Sb<sub>3</sub>O<sub>4</sub> separated by isolated iodine ions. The two phases differ only in the next nearest neighbour arrangement. The orthorhombic α-phase crystallizes in space group Pbn2<sub>1</sub>, and the monoclinic β-phase in space group P2<sub>1</sub>/n.</p>}}, author = {{Hugonin, Zuzana and Johnsson, Mats and Lidin, Sven}}, issn = {{1293-2558}}, keywords = {{Multiphase crystal; Oxo-halide; Stereochemically active lone pair}}, language = {{eng}}, month = {{01}}, number = {{1}}, pages = {{24--28}}, publisher = {{Elsevier}}, series = {{Solid State Sciences}}, title = {{Two for the price of one - Resolvable polymorphism in a 'single crystal' of α- and β-Sb<sub>3</sub>O<sub>4</sub>I}}, url = {{http://dx.doi.org/10.1016/j.solidstatesciences.2008.04.028}}, doi = {{10.1016/j.solidstatesciences.2008.04.028}}, volume = {{11}}, year = {{2009}}, }