Oxygen-Stabilized Rh Adatoms: 0D Oxides on a Vicinal Surface
(2011) In The Journal of Physical Chemistry Letters 2(21). p.2747-2751- Abstract
- We have investigated the initial oxidation of the Rh(113) and Rh(223) vicinal surfaces by STM and ab initio simulations. Upon adsorption of small amounts of oxygen, the surface morphology is completely altered. Surprisingly, oxygen-stabilized Rh adatoms can be observed on the (113) facets, with oxide-like electronic properties. We present models of these "0D oxide" phases and discuss reasons for their stability.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2254430
- author
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of Physical Chemistry Letters
- volume
- 2
- issue
- 21
- pages
- 2747 - 2751
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000296597700015
- scopus:80455158221
- ISSN
- 1948-7185
- DOI
- 10.1021/jz2011308
- language
- English
- LU publication?
- yes
- id
- 49043d8a-4806-4cb6-8688-2463ccca1f2a (old id 2254430)
- date added to LUP
- 2016-04-01 13:31:47
- date last changed
- 2023-09-17 01:23:03
@article{49043d8a-4806-4cb6-8688-2463ccca1f2a, abstract = {{We have investigated the initial oxidation of the Rh(113) and Rh(223) vicinal surfaces by STM and ab initio simulations. Upon adsorption of small amounts of oxygen, the surface morphology is completely altered. Surprisingly, oxygen-stabilized Rh adatoms can be observed on the (113) facets, with oxide-like electronic properties. We present models of these "0D oxide" phases and discuss reasons for their stability.}}, author = {{Mittendorfer, Florian and Franz, Thomas and Klikovits, Jan and Schmid, Michael and Merte, Lindsay R. and Zaman, Sameena Shah and Varga, Peter and Westerström, Rasmus and Resta, Andrea and Andersen, Jesper N and Gustafson, Johan and Lundgren, Edvin}}, issn = {{1948-7185}}, language = {{eng}}, number = {{21}}, pages = {{2747--2751}}, publisher = {{The American Chemical Society (ACS)}}, series = {{The Journal of Physical Chemistry Letters}}, title = {{Oxygen-Stabilized Rh Adatoms: 0D Oxides on a Vicinal Surface}}, url = {{http://dx.doi.org/10.1021/jz2011308}}, doi = {{10.1021/jz2011308}}, volume = {{2}}, year = {{2011}}, }