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Ioniclike energy structure of neutral core-excited states in free Kr clusters

Peredkov, Sergey LU ; Kivimaki, A ; Ristinmaa Sörensen, Stacey LU ; Schulz, Joachim LU ; Mårtensson, Nils LU ; Öhrwall, Gunnar LU orcid ; Lundwall, M ; Rander, T ; Lindblad, A and Bergersen, H , et al. (2005) In Physical Review A (Atomic, Molecular and Optical Physics) 72(2).
Abstract
The development of electronic states in krypton clusters is investigated by high-resolution core-level electron spectroscopy. The energy ordering of bulk versus surface 3d(-1)np(n > 5) core-excited states in neutral clusters is demonstrated to be reversed to the 3d(-1)5p level situation. The cluster 3d(-1)6p,7p states are proven to be at a lower energy than the corresponding atomic levels. These findings reveal the ioniclike energy structure of the neutral cluster core-excited levels. The phenomenon is explained by a spatial spread of the excited orbitals over the cluster lattice.
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Physical Review A (Atomic, Molecular and Optical Physics)
volume
72
issue
2
article number
021201(R)
publisher
American Physical Society
external identifiers
  • wos:000231564200010
  • scopus:27144503065
ISSN
1050-2947
DOI
10.1103/PhysRevA.72.021201
language
English
LU publication?
yes
id
adce971c-69a9-40e2-ac86-7242d08aac49 (old id 226163)
date added to LUP
2016-04-01 12:26:25
date last changed
2022-01-27 03:44:07
@article{adce971c-69a9-40e2-ac86-7242d08aac49,
  abstract     = {{The development of electronic states in krypton clusters is investigated by high-resolution core-level electron spectroscopy. The energy ordering of bulk versus surface 3d(-1)np(n > 5) core-excited states in neutral clusters is demonstrated to be reversed to the 3d(-1)5p level situation. The cluster 3d(-1)6p,7p states are proven to be at a lower energy than the corresponding atomic levels. These findings reveal the ioniclike energy structure of the neutral cluster core-excited levels. The phenomenon is explained by a spatial spread of the excited orbitals over the cluster lattice.}},
  author       = {{Peredkov, Sergey and Kivimaki, A and Ristinmaa Sörensen, Stacey and Schulz, Joachim and Mårtensson, Nils and Öhrwall, Gunnar and Lundwall, M and Rander, T and Lindblad, A and Bergersen, H and Svensson, S and Bjorneholm, O and Tchaplyguine, Maxim}},
  issn         = {{1050-2947}},
  language     = {{eng}},
  number       = {{2}},
  publisher    = {{American Physical Society}},
  series       = {{Physical Review A (Atomic, Molecular and Optical Physics)}},
  title        = {{Ioniclike energy structure of neutral core-excited states in free Kr clusters}},
  url          = {{http://dx.doi.org/10.1103/PhysRevA.72.021201}},
  doi          = {{10.1103/PhysRevA.72.021201}},
  volume       = {{72}},
  year         = {{2005}},
}