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Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.

Johnsson, Richard LU (2012) In Carbohydrate Research 353(Online 24 March 2012). p.92-95
Abstract
The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Carbohydrate Research
volume
353
issue
Online 24 March 2012
pages
92 - 95
publisher
Elsevier
external identifiers
  • wos:000304053900012
  • pmid:22533917
  • scopus:84861096808
  • pmid:22533917
ISSN
1873-426X
DOI
10.1016/j.carres.2012.03.016
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
be34b210-aeb0-4f39-9047-68a81a33d067 (old id 2519040)
date added to LUP
2016-04-01 10:32:21
date last changed
2022-02-17 19:03:31
@article{be34b210-aeb0-4f39-9047-68a81a33d067,
  abstract     = {{The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-d-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-d-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.}},
  author       = {{Johnsson, Richard}},
  issn         = {{1873-426X}},
  language     = {{eng}},
  number       = {{Online 24 March 2012}},
  pages        = {{92--95}},
  publisher    = {{Elsevier}},
  series       = {{Carbohydrate Research}},
  title        = {{Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.}},
  url          = {{https://lup.lub.lu.se/search/files/1930479/2539511.pdf}},
  doi          = {{10.1016/j.carres.2012.03.016}},
  volume       = {{353}},
  year         = {{2012}},
}